Use the expression we obtained in class to write the molar absorption coefficient of a particular transition in terms of the transition dipole moment of the transition. If the transition dipole moment is tripled in value, how would the molar absorption coefficient change

Answers

Answer 1

Answer:

Initially the function is symmetric with respect to the axis of the one dimensional box. In the final state it is also symmetrical, however you can envision a snapshot of the system as the light field is interacting with the wave-function wherein a node begins to develop as is shown in the middle and the wave function is evolving from the initial to final state. Now consider that the electron density during process is the square of the wave function:

Electron density during transition

As can be seen in the initial and final states the electron density is symmetrically distributed with respect to the axis of the box. However with the field on, the electron density is not symmetrically distributed and a transitory dipole moment can be present. To relate back to real molecules think of each of those orbitals as a linear combination of atomic orbitals. One important factor is the symmetry. But there may be one other factor that will be just as important as symmetry. If you treat orbital 1 as a linear combination over n orbitals and orbital 2 as a linear combinations of orbitals as well, there will be a spatial over lap between the orbital in the ground state and the orbital in the excited state. If there is no spatial overlap between the ground state and excited state orbitals there will be no transition dipole moment. However, if the electrons are in the same place spatially, a large transition dipole moment will result.

Explanation:


Related Questions

1.2 What type of bonding occurs when hydrogen form a diatomic molecule?​

Answers

Answer:

I think it is covalent bonding...

Explanation:

The bonding is covalent in homonuclear diatomic molecules. Each atom in the molecule has the same electronegativity, which means electrons are shared equally between the two. The electronegativity of the atoms in heteronuclear diatomic molecules varies, and these molecules have polar covalent bonds. A dipole is formed when a molecule interacts with another molecule. (i think it's covalent bonding but i might be wrong)

hope this helps...

A covalent bond! A hydrogen molecule forms from two hydrogen atoms, each with one electron in a 1 s orbital. The two hydrogen atoms are attracted to the same pair of electrons in the covalent bond. A covalent bond is the force of attraction that holds together two atoms that share a pair of electrons. The shared electrons are attracted to the nuclei of both atoms. Covalent bonds form only between atoms of nonmetals. The two atoms may be the same or different elements. If the bonds form between atoms of different elements, a covalent compound forms.

There are three types
of atoms, which on gains and looses electrons?

Answers

Answer:

https://courses.lumenlearning.com/boundless-biology/chapter/atoms-isotopes-ions-and-molecules/

Explanation:

Which process created the gases of earth’s first atmosphere?

a.volcanic activity
b.weathering
c.photosynthesis
d.photolysis

Answers

Answer:

Volcanic Activity

Explanation:

Answer: A) Volcanic Activity

Does all of the liquid water in the atmosphere fall as rain? Why or why not?

Answers

Most of the condensed water in clouds does not fall as precipitation because their fall speed is not large enough to overcome updrafts which support the clouds. ... Water droplets may grow as a result of additional condensation of water vapor when the particles collide.

Do you think baking a cake is or is not a chemical reaction

Answers

Answer:

yes

Explanation:

its an endothermic chemical reaction

Answer:

It is a chemical reaction because you cannot get back the original ingredients. if you can get the original ingredients back, it would be a physical change.

Hope this helped you out!!

How many moles of O2 are dissolved n 10.0 L of a 0.001 mol dm-3 solution?

Answers

Answer:

[tex]0.01molO_2[/tex]

Explanation:

Hello there!

In this case, by considering the definition of molar solution as the moles of solute over volume in liters or cubic meters of solution, we can see that actually 10.0 L of the solution are equal to 10.0 dm³. In such a way, since the concentration is 0.001 mol / dm³, the moles of oxygen that are dissolved turn out to be:

[tex]0.001mol/dm^3 * 10.0dm^3\\\\0.01molO_2[/tex]

Best regards!

2. Why can we eliminate the claim you circled?

Answers

Answer: theres no image or claim

what is the circles claim

Rock formations are sculpted into shape by two general forces. What are these?

a.photosynthesis and volcanism
b.weathering and erosion
c.volcanism and weathering
d.uplift and rainfall

Answers

Answer:weathering and erosion

Please mark brainlyest

Explanation:

Answer:

b.weathering and erosion

Explanation:

Weathering and erosion shape rock formations.

Aqueous hydrochloric acid will react with solid sodium hydroxide to produce aqueous sodium chloride and liquid water . Suppose 1.5 g of hydrochloric acid is mixed with 2.67 g of sodium hydroxide. Calculate the maximum mass of water that could be produced by the chemical reaction. Round your answer to significant digits.

Answers

Answer: The maximum amount of water that can be produced is 0.74 g

Explanation:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]      .....(1)  

Putting values in equation 1, we get:

[tex]\text{Moles of hydrochloric acid:}=\frac{1.5g}{36.5g/mol}=0.041mol[/tex]

[tex]\text{Moles of sodium hydroxide}=\frac{2.67g}{40g/mol}=0.067mol[/tex]

The chemical equation for the reaction is

[tex]HCl+NaOH\rightarrow NaCl+H_2O[/tex]

By Stoichiometry of the reaction:

1 mole of HCl reacts with 1 mole of NaOH

So, 0.041 moles of HCl will react with = [tex]\frac{1}{1}\times 0.041=0.041mol[/tex] of NaOH

As, given amount of NaOH is more than the required amount. So, it is considered as an excess reagent. Thus, HCl is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

1 mole of HCl produces = 1 mole of water

So, 0.041 moles of HCl will produce = [tex]\frac{1}{1}\times 0.041=0.041moles[/tex] of water

Mass of water=[tex]moles\times {\text{Molar Mass}}=0.041mol\times 18g/mol=0.74g[/tex]

Thus the maximum amount of water that can be produced is 0.74 g

6.An ice cube that has a mass of 20 g is in a sealed container. As the container is heated, the ice first melts, but eventually it changes to water vapor.

A)The temperature at which the ice melts is ____________________.

B) Compare the motion of the particles in each state

Answers

Answer:

See explanation

Explanation:

a) Every substance melts at a particular temperature known as the melting point of the substance. The melting point of ice is 0°C. Hence ice melts at  0°C.

b) There are three states of matter; solid liquid and gas. The particles of matter in each stage of matter possess varying degrees of freedom.

In the solid state, the intermolecular forces between the particles of water that compose ice are very strong. Hence the particles do not translate, they only vibrate or rotate about their mean positions.

In the liquid state, the magnitude of intermolecular interaction is less than that of the solids hence the molecules can translate but not with a high kinetic energy.

In the gaseous state, there is a minimum intermolecular interaction between particles theoretically hence the particles are really free to move about with a very high kinetic energy.

KBr(aq) + NaCl(aq) =

Answers

It’s ionic
KCl(at)
Potassium chloride

make a chart to show the effect of Sodium Hydroxide and Sulphuric acid on methyl orange and red litmus paper​

Answers

Answer:

mark me as brainliest plsss

Hence in the Sodium hydroxide, methyl orange will turn into yellow color and in Sulfuric acid shows red color. Red litmus will turn into blue color in the Sodium hydroxide solution.

What is litmus paper?

Litmus paper is a paper which is used to identify the acidity or basicity of any solution.

Sulfuric acid is acidic in nature, and red litmus paper shows no effect in this acid as red paper change into blue in the presence of base. Methyl orange is an indicator and it shows red color in the acidic medium.Sodium hydroxide is basic in nature and red litmus paper will change into blue in this solution and color of methyl orange changes from red to yellow in the basic solution.

Hence, the effect of red litmus & methyl orange is explained above.

To know more about litmus paper, visit the below link:
https://brainly.com/question/1287856

A gas system contains 2.00 moles of O2 and CO2 gas, has an initial temperature of 25.0 oC and is under 1.00 atm of pressure. If the pressure remains constant and the temperature is raised to 45.0 oC, then what will the new volume (assuming a closed system) be?

Answers

Answer:

[tex]V_2=52.2L[/tex]

Explanation:

Hello there!

In this case, by bearing to to mind the given conditions, it is firstly possible to determine the initial volume of the closed system via the ideal gas equation:

[tex]PV=nRT\\\\V=\frac{2.00mol*0.08206\frac{atm*L}{mol*K}*298.15K}{1.00 atm} \\\\V=48.9L[/tex]

Which is V1 in the Charles' law:

[tex]\frac{T_2}{V_2} =\frac{T_1}{V_1}[/tex]

And of course, T1 is 298.15 (25+273.15). Therefore, by solving for V2 as the final volume, we obtain:

[tex]V_2=\frac{V_1T_2}{T_1}\\\\V_2=\frac{48.9L*(45+273.15)K}{(25+273.15)K} \\\\V_2=52.2L[/tex]

Best regards!

4.4 mol nitrogen.

VN2 = ____L

Answers

Answer:

99 L

Explanation:

Step 1: Given data

Moles of nitrogen: 4.4 moles

Step 2: Calculate the volume occupied by 4.4 moles of nitrogen

The volume occupied by a gas depends on other conditions such as pressure  (P) and temperature (T). If we have this information, we can calculate the volume of the gas using the ideal gas condition.

P × V = n × R × T

Since the task doesn't inform the conditions, we can assume it is under standard pressure (1 atm) and temperature (273.15 K). At STP, 1 mole of any gas occupies 22.4 L.

4.4 mol × 22.4 L/1 mol = 99 L

t-Butyl alcohol (TBA) is an important octane enhancer that is used to replace lead additives in gasoline.

a. True
b. False

Answers

Answer:

True

Explanation:

The correct option is - True

For each of the following precipitation reactions, complete and balance the equation, indicating clearly which product is the precipitate.
a) Ba(NO3)2(aq) + (NH4)2SO4(aq)
b)CoCl3(aq) + NaOH(aq)
c)FeCl3(aq) + (NH4)2SS(aq)

Answers

Answer:

a) Ba(NO₃)₂(aq) + (NH₄)₂SO₄(aq) ⇒ 2 NH₄NO₃(aq) + BaSO₄(s)

b) CoCl₃(aq) + 3 NaOH(aq) ⇒ 3 NaCl(aq) + Co(OH)₃(s)

c) 2 FeCl₃(aq) + 3 (NH₄)₂S(aq) ⇒ 6 NH₄Cl(aq) + Fe₂S₃(s)

Explanation:

We have 3 double displacement reactions, in which both reactants exchange their cations and anions, and an insoluble compound is formed and precipitates as a solid. This is indicated as (s).

a) Ba(NO₃)₂(aq) + (NH₄)₂SO₄(aq) ⇒ 2 NH₄NO₃(aq) + BaSO₄(s)

b) CoCl₃(aq) + 3 NaOH(aq) ⇒ 3 NaCl(aq) + Co(OH)₃(s)

c) 2 FeCl₃(aq) + 3 (NH₄)₂S(aq) ⇒ 6 NH₄Cl(aq) + Fe₂S₃(s)

In the front of the room, there is a bottle that contains a 32.00 g sample of sulfur. This is
1 mole of sulfur. Estimate how many atoms are in the bottle.

Answers

6.02x10^23 atoms is the answer

Equation: CH4 + 202 CO2 + 2H20

What is the mole ratio between oxygen and methane (CH4)? If you use 15 moles of 02, how many grams of methane would you predict would be needed?

Answers

Answer:

2:1

1.2 × 10² g

Explanation:

Step 1: Write the balanced combustion equation

CH₄ + 2 O₂ ⇒ CO₂ + 2 H₂O

Step 2: Establish the appropriate molar ratio

According to the balanced equation, the molar ratio of O₂ to CH₄ is 2:1.

Step 3: Calculate the moles of CH₄ required to react with 15 moles of O₂

We will use the previously established molar ratio.

15 mol O₂   1 mol CH₄/2 mol O₂ = 7.5 mol CH₄

Step 4: Calculate the mass corresponding to 7.5 moles of CH₄

The molar mass of CH₄ is 16.04 g/mol.

7.5 mol × 16.04 g/mol = 1.2 × 10² g

A chemist fills a reaction vessel with 0.247 M lead(II) (Pb2+) aqueous solution, 0.758 M bromide (Br-) aqueous solution, and 0.109 g lead (II) bromide (PbBr2) solid at a temperature of 20.0 oC. Under these conditions, calculate the reaction free energy deltaG for the following chemical reaction:
Pb2+(aq) + 2Br-(aq) <----> PbBr2(s)

Answers

Answer:

ΔG = -24.7kJ/mol

Explanation:

ΔG° of

Pb2+(aq) + 2Br-(aq) ⇄ PbBr2(s)

is:

ΔG° PbBr2 - (2*ΔG°Br- + ΔG°Pb2+)

-261.9kJ/mol - (2*-104.0kJ/mol + -24.4kJ/mol) =  

-29.5kJ/mol

ΔG of the reaction is:

ΔG = ΔG° + RT lnQ

Where R is gas constant (8.314x10⁻³kJ/molK)

T is absolute temperature (20°C + 273.15 = 293.15K)

Q is reaction quotient = 1 / [Pb²⁺][Br⁻]²

Replacing:

ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [Pb²⁺][Br⁻]²)

ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [0.247M][0.758M]²)

ΔG = -24.7kJ/mol

Which of these things would you expect to have cells with both mitochondria
and chloroplasts?
A. Squirrel
B. Shark
C. Hummingbird
D. Grass​

Answers

Answer:

D. Grass​

Explanation:

Every living organism must contain one or more cells to be considered "living". Each cell, however, contains certain structures that perform specific roles called ORGANELLES. These organelles are of different types and hence, perform different tasks. For example, mitochondria is the power house of a cell i.e. site of energy production, and hence, is found in every eukaryotic cell.

On the other hand, chloroplast is an organelle designed to perform photosynthesis, which only occurs in plant cells. Since only plant cells can undergo photosynthesis, only plant cells can contain chloroplast. Hence, according to this question, GRASS as a type of plant is an organism that will contain both mitochondria and chloroplast in its cells.

3. The graph below shows the temperature changes occurring in two hot packs that are made from different materials. The same amounts of water and CaCl2 were used to make each pack. Which of the following inferences is supported by the graph?

Answers

Answer:

LDPE would be the best choice for a hand warmer designed to release heat quickly.

Explanation:

Judging from the graph, the LDPE plastic releases heat quicker than the Latex. (and I also did the gizmo-)

Temperature is a property of matter that represents the amount of energy expended in the motion of the constituent particles.

What is matter?

Matter is any substance that has mass and takes up space by having volume.

What is energy?

The potential to work would be defined as energy.

What is motion?

The definition of motion is still the change in the position and orientation of the body over time.

As a result, the highest temperature of latex is approximately 530°C, while the temperature of LDPE plastic becomes 58°C in the graph above. After 60 minutes, the LDPE plastic will emit less energy toward its surroundings than latex. Latex reaches its highest temperature faster than LDPE plastic.

To learn more about energy and motion click here

https://brainly.com/question/2748259.

#SPJ2

how many electrons do nonmetals atoms tend to gain when forming ions

Answers

Since nonmetals have five, six, or seven electrons in their valence shells, it takes less energy to gain the necessary electrons, and therefore form anions.

PLS HELP

True or false?
If a negatively charged particle is attracted to a second particle, the second particle must have a negative charge

Answers

Answer:

False

Explanation:

Negatively charged particles repel other negatively charged particles. Typically a negatively charged particle is electropositive and wants a positive molecule and/or cation (positive ion) to form a bond with. Negative molecules want positive molecules and vise versa.

Organelles that use energy from sunlight to produce food are called mitochondria
O True
O False​

Answers

Answer:

Organelles that use energy from sunlight to produce food are called mitochondria.

False

a sample of gas has a volume of 100.0L at 135C assuming the pressure remains constant

Answers

Answer:  84.56 L is the answer.

Explanation:

Answer:

84.6

Explanation:

I took the test

A student ran the following reaction in the laboratory at 1100 K: 2SO2(g) O2(g) 2SO3(g) When he introduced SO2(g) and O2(g) into a 1.00 L evacuated container, so that the initial partial pressure of SO2 was 3.43 atm and the initial partial pressure of O2 was 1.61 atm, he found that the equilibrium partial pressure of O2 was 0.809 atm. Calculate the equilibrium constant, Kp, she obtained for this reaction.

Answers

Answer:

Kp = 0.949

Explanation:

Hello there!

In this case, according to the given chemical reaction:

[tex]2SO_2(g) +O_2(g) \rightleftharpoons 2SO_3(g)[/tex]

It is possible to set up the equilibrium expression as shown below:

[tex]Kp=\frac{p_{SO_3}^2}{p_{SO_2}^2p_{O_2}}[/tex]

Whereas the initial pressure of SO2 was 3.43 atm and that of O2 was 1.61 atm. Now, since the partial pressure of O2 decreased to the 0.809 atm, it is possible to calculate the change in the pressure of O2 via:

[tex]x=1.61atm-0.809atm=0.801atm[/tex]

Which is actually applied to SO3 and SO2 according to the stoichiometry in the equilibrium expression to calculate Kp:

[tex]Kp=\frac{(2*x)^2}{(3.43-2x)^2(0.809)}[/tex]

Thus, by plugging in x, we obtain:

[tex]Kp=\frac{(2*0.801)^2}{(3.43-2*0.801)^2(0.809)}\\\\Kp=0.949[/tex]

Best regards!

Where is chemical energy contained in a compound?
A. in the movement of the electrons
B. in the nuclei
C. in the bonds
D. in unbonded electrons

Answers

Answer:

C

Explanation:

Energy stored in the bonds of chemical compounds. Chemical energy may be released during a chemical reaction, often in the form of heat; such reactions are called exothermic.

Answer:

The Answer is C.

Explanation:

Cause I'm smart

Encountering problems during separation/purification is a very common issue in organic synthesis, but these steps are crucial to isolate your desired product.

a. True
b. False

Answers

true is the correct answer! your welcome! :)

A study was created to test the effects of fear in children. The hypothesis of the experimenters was that if babies were exposed to fuzzy bunnies and at the same time a loud cymbal was struck close behind them, then that child would be afraid of all fuzzy things. Another group of children would be exposed to bunnies without any loud noises. The study was carried out as planned and as a result, hundreds of young children developed fear of all cute furry bunny rabbits.

Dependent Variable: ______________________

Control Group: ____________________________

Independent Variable: _____________________

Experimental Group: _______________________

Answers

Answer:

Dependent variable: the children's fear of rabbits

Control: the group that was NOT exposed to loud noises

Independent variable: the loud noises

Experimental Group: the group that was exposed to loud noises

Which one of the following statements concerning the length of carbon-carbon single, double, and triple covalent bonds is true?

A. The carbon-carbon single bond is shorter than either the carbon-carbon double or triple bond.
B. The carbon-carbon double bond is shorter than either the carbon-carbon single or triple bond.
C. The carbon-carbon triple bond is shorter than either the carbon-carbon single or double bond.
D. The carbon-carbon single, double, and triple bonds all have the same length.

Answers

Answer:

[tex]\color{Blue}\huge\boxed{Question} [/tex]

Which one of the following statements concerning the length of carbon-carbon single, double, and triple covalent bonds is true?

[tex]\color{Blue}\huge\boxed{Answer} [/tex]

D. The carbon-carbon single, double, and triple bonds all have the same length.

The statement concerning the length of carbon-carbon single, double, and triple covalent bonds which is true is: D. The carbon-carbon single, double, and triple bonds all have the same length.

A chemical bond can be defined as the forces of attraction between ions, crystals, atoms or molecules which are typically responsible for the formation of chemical compounds. Thus, a chemical bond is a force that holds atom together and binds crystals, ions or molecules together, so as to form a chemical compound.

Generally, there are three (3) main types of chemical bonds and these includes:

Hydrogen bonds.Ionic bonds.Covalent bonds.

A covalent bond can be defined as a type of bond that typically involves the sharing of electrons between the atoms of a chemical element. The type of bond formed between two or more carbon atoms is a covalent bond. Hence, carbon atoms can either form a single, double, or triple covalent bonds with the same length.

In conclusion, the length of carbon-carbon single, double, and triple covalent bonds are all the same.

Read more: https://brainly.com/question/24212500

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