How many grams of KClO3 must be decomposed to produce 3. 45 L of oxygen at STP with a 75. 3% yield? 2 KClO3(s) à 2 KCl(s) + 3 O2(g)

Answers

Answer 1

16.77 grams of KClO3 must be decomposed to produce 3.45 L of oxygen at STP with a 75.3% yield.

To find out how many grams of KClO3 must be decomposed to produce 3.45 L of oxygen at STP with a 75.3% yield, we'll use the following steps:

1. Convert the volume of oxygen gas to moles using the molar volume of gas at STP (22.4 L/mol).
2. Adjust for the yield percentage.
3. Use the stoichiometry of the balanced equation to find the moles of KClO3.
4. Convert moles of KClO3 to grams using its molar mass.

1. Moles of O2 produced: (3.45 L) / (22.4 L/mol) = 0.154 moles O2
2. Adjust for yield: 0.154 moles / 0.753 = 0.205 moles O2 (theoretical yield)
3. Moles of KClO3: (0.205 moles O2) * (2 moles KClO3 / 3 moles O2) = 0.137 moles KClO3
4. Grams of KClO3: (0.137 moles KClO3) * (122.55 g/mol) = 16.77 g KClO3

So, 16.77 grams of KClO3 must be decomposed to produce 3.45 L of oxygen at STP with a 75.3% yield.

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Related Questions

3. why is a one molal solution


easier to prepare than a one


molar solution?

Answers

A one molal solution is easier to prepare.

A one molal solution is easier to prepare than a one molar solution because it involves a smaller amount of solute. A one molar solution contains one mole of solute per liter of solution, while a one molal solution contains one mole of solute per kilogram of solvent. Since a kilogram of solvent is usually easier to measure than a liter of solution, it is easier to prepare a one molal solution. Additionally, the concentration of a one molal solution is dependent on the mass of solvent, which is more consistent and precise than the volume of solution.

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If 450. 5 calories of heat energy are added to a 89. 6 gram sample of aluminium (specific heat of 0. 215 calories per gram degree celsius) and the initial temperature of the sample is 25. 7 degrees celsius then what is the final temperature in degrees celsius?​

Answers

The final temperature of an 89.6 gram sample of aluminum is calculated to be 30.6°C after 450.5 calories of heat energy is added, given that the specific heat of aluminum is 0.215 calories per gram degree Celsius and the initial temperature is 25.7°C.

To solve this problem, we can use the formula:

Q = m x c x ΔT

where Q is the amount of heat energy added, m is the mass of the sample, c is the specific heat of the material, and ΔT is the change in temperature.

We are given Q = 450.5 calories, m = 89.6 grams, c = 0.215 calories per gram degree Celsius, and the initial temperature of the sample T1 = 25.7°C.

Let's assume that the final temperature of the sample is T2. Therefore, we can write:

Q = m x c x (T2 - T1)

Solving for T2, we get:

T2 = (Q/mc) + T1

Substituting the given values, we get:

T2 = (450.5 calories)/(89.6 grams x 0.215 calories per gram degree Celsius) + 25.7°C

T2 = 30.6°C

Therefore, the final temperature of the sample is 30.6°C.

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Use the following information to answer the following question

The following is a list of solutions that can be considered acids:

1.CH3COOH(aq)
2.HI(aq)
3.H2O(aq)
4.H₂CO3(aq)
5.HCOOH(aq)
6.NaHSO3(aq)

Match the following conditions to the acids listed above

__Acid with the highest electrical conductivity

__Acid which could also be a base according to the Modified Arrhenius Theory

__Polyprotic acid

__Ionizes at a rate of 2 ppb

Answers

The matchup are:

Acid with the highest electrical conductivity: HCl(aq)Acid which could also be a base according to the Modified Arrhenius Theory: H2O(aq)Polyprotic acid: H2CO3(aq)Ionizes at a rate of 2 ppb: HCOOH(aq)

What are the acids?

Acid with the highest electrical conductivity:

HCl(aq) has the highest electrical conductivity among common acids because it completely dissociates into H+ and Cl- ions in water, making it a strong acid. This means that it can conduct electricity very effectively in solution.

Acid which could also be a base according to the Modified Arrhenius Theory:

The Modified Arrhenius Theory defines an acid as a substance that donates protons (H+) in solution, and a base as a substance that accepts protons. While H2O(aq) is commonly thought of as a neutral substance, it can actually act as an acid or a base in certain

Note:  H2O(aq) is amphoteric, meaning it can act as an acid or a base according to the Modified Arrhenius Theory. H2CO3(aq) is a polyprotic acid, meaning it can donate multiple protons in a stepwise manner. HCOOH(aq) has a very low ionization constant, meaning it ionizes at a very slow rate compared to other acids.

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consider 5 sequential reactions where the product of each reaction is the reactant of the next and the 5 percent yields are 80%, 90%, 65%, 76% and 30%. if you begin with 100 molecules of the first limiting reagent, what is the maximum number of product molecules you can form at the end of the final reaction? \textbf{hint:} remember that you cannot have parts of a molecule!

Answers

Starting with 100 molecules of the first limiting reagent, the maximum number of product molecules that can be formed at the end of the final reaction, given the yields of each reaction, is 11 molecules.

Let's call the starting number of molecules of the first limiting reagent "A". Then, the number of molecules of each reactant and product after each reaction can be represented as follows,

Reaction 1: A → B (80% yield)

Starting molecules of A = 100

Molecules of B produced = 80

Reaction 2: B → C (90% yield)

Starting molecules of B = 80

Molecules of C produced = 72

Reaction 3: C → D (65% yield)

Starting molecules of C = 72

Molecules of D produced = 46.8 (rounded to 47)

Reaction 4: D → E (76% yield)

Starting molecules of D = 47

Molecules of E produced = 35.72 (rounded to 36)

Reaction 5: E → F (30% yield)

Starting molecules of E = 36

Molecules of F produced = 10.8 (rounded to 11)

Therefore, the maximum number of product molecules that can be formed at the end of the final reaction is 11, rounded to the nearest whole number.

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The decomposition reaction of calcium carbonate is represented by the following balanced equation:


CaCO3(s) --> CaO(s) + CO2(g)



After a 15. 8−g sample of calcium carbonate was heated in an open container to cause decomposition, the mass of the remaining solid was determined to be 9. 10 g. The reaction may or may not have gone to completion, so the solid could contain unreacted CaCO3. Calculate the percent yield of CO2.



Please help! Thank you!

Answers

The percent yield of CO2 in the decomposition reaction of calcium carbonate is 96.20%.

The decomposition reaction of calcium carbonate (CaCO3) is represented by the balanced equation:

CaCO3(s) --> CaO(s) + CO2(g)

To calculate the percent yield of CO2 from a 15.8-g sample of calcium carbonate that decomposed, leaving a solid mass of 9.10 g, follow these steps:

1. Determine the molar mass of CaCO3, CaO, and CO2.
- CaCO3: (40.08 + 12.01 + 3*16.00) = 100.09 g/mol
- CaO: (40.08 + 16.00) = 56.08 g/mol
- CO2: (12.01 + 2*16.00) = 44.01 g/mol

2. Calculate the theoretical amount of CO2 produced by the complete decomposition of 15.8 g of CaCO3.
- moles of CaCO3: (15.8 g) / (100.09 g/mol) = 0.158 mol
- moles of CO2 produced: 0.158 mol (1:1 ratio with CaCO3)
- mass of CO2: (0.158 mol) * (44.01 g/mol) = 6.95 g

3. Calculate the actual amount of CO2 produced based on the remaining solid mass.
- mass of CaO and unreacted CaCO3: 9.10 g
- mass of CaCO3 in the remaining solid: 15.8 g - 9.10 g = 6.70 g
- moles of CO2 actually produced: (6.70 g) / (44.01 g/mol) = 0.152 mol

4. Calculate the percent yield of CO2.
- percent yield: (actual moles of CO2 / theoretical moles of CO2) * 100
- percent yield: (0.152 mol / 0.158 mol) * 100 = 96.20%

The percent yield of CO2 in the decomposition reaction of calcium carbonate is 96.20%.

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2H2 + 1O2 --> 2H2O


Suppose you had 20. 76 moles of H2 on hand and plenty of O2, how many moles of H2O could you make?

Answers

When given 20.76 moles of H2 and plenty of O2, you can make 20.76 moles of H2O.

To determine how many moles of H2O can be produced from 20.76 moles of H2 and plenty of O2, we'll use the balanced chemical equation provided: 2H2 + 1O2 --> 2H2O.

Step 1: Identify the limiting reactant. In this case, we have plenty of O2, so H2 is the limiting reactant.

Step 2: Determine the mole ratio between the limiting reactant (H2) and the product (H2O). According to the balanced equation, the mole ratio is 2H2 to 2H2O, or 1:1.

Step 3: Calculate the moles of H2O produced. Since the mole ratio is 1:1, the number of moles of H2O produced will be the same as the number of moles of H2 available. Thus, you can produce 20.76 moles of H2O.

In summary, when given 20.76 moles of H2 and plenty of O2, you can make 20.76 moles of H2O.

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A liquid hydrocarbon has an empirical formula CCl2 and a boiling point of 121°C, when vaporized the gaseous compound has a density of 4. 93g/L at 785 torr and 150°C. What is the molar mass the compound and what is the molecular weight?

Answers

The molecular weight of the hydrocarbon is 165.83 g/mol and its molecular formula is[tex]C2Cl4[/tex].

Since the empirical formula of the hydrocarbon is [tex]CCl2[/tex], we can assume that it contains one carbon atom and two chlorine atoms.

Let's first calculate the molar mass of the empirical formula:

The atomic weight of carbon is 12.01 g/mol

The atomic weight of chlorine is 35.45 g/mol

The empirical formula mass is therefore 12.01 g/mol + 2(35.45 g/mol) = 83.91 g/mol

To find the molecular formula, we need to know the molecular weight of the compound. We can use the ideal gas law to calculate the number of moles of the gas:

PV = nRT

where P is the pressure in atmospheres, V is the volume in liters, n is the number of moles, R is the ideal gas constant (0.0821 L·atm/mol·K), and T is the temperature in Kelvin.

First, we need to convert the pressure from torr to atm:

785 torr = 1.036 atm

We also need to convert the temperature from Celsius to Kelvin:

150°C + 273.15 = 423.15 K

Now we can solve for the number of moles:

n = PV/RT

n = (1.036 atm)(4.93 g/L)/(0.0821 L·atm/mol·K)(423.15 K)

n = 0.208 mol

The molar mass of the compound is the mass divided by the number of moles:

mass = n × molar mass

molar mass = mass / n

molar mass = (0.208 mol) × (4.93 g/L) / (1 L/mol)

molar mass = 1.025 g/mol

Finally, we can find the molecular formula by comparing the molar mass of the empirical formula to the molar mass of the compound:

molecular weight / empirical formula weight = n

where n is an integer. We can calculate n as follows:

n = molecular weight / empirical formula weight

n = 1.025 g/mol / 83.91 g/mol

n = 0.0122

n is close to 1/2, so we can double the empirical formula to get the molecular formula:

[tex]C2Cl4[/tex]

Therefore, the molecular weight of the hydrocarbon is 165.83 g/mol (2 × 83.91 g/mol) and its molecular formula is [tex]C2Cl4[/tex].

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Use the VSEPR Theory to predict the molecular geometry of the following molecules:


(Remember, you may need to draw the lewis structure before making a prediction. )




HI




CBr4




CH2Cl2




SF2




PCl3

Answers

To predict the molecular geometry of these molecules using the VSEPR theory, we first need to draw the Lewis structure for each molecule:

1. HI

Lewis structure: H-I (single bond)

The central atom (Iodine) has 7 valence electrons, and each hydrogen atom contributes 1 valence electron. Therefore, the total valence electrons in the molecule is 9.

Steric number = number of lone pairs of electrons + number of atoms bonded to central atom = 0 + 1 = 1

Molecular geometry: linear

2. CBr4

Lewis structure:

:Br-C-Br:

: | :

:Br-C-Br:

The central atom (Carbon) has 4 valence electrons, and each Bromine atom contributes 7 valence electrons. Therefore, the total valence electrons in the molecule is 32.

Steric number = number of lone pairs of electrons + number of atoms bonded to central atom = 0 + 4 = 4

Molecular geometry: tetrahedral

3. CH2Cl2

Lewis structure:

H : Cl

| :

H-C-H

| :

Cl:

The central atom (Carbon) has 4 valence electrons, each hydrogen atom contributes 1 valence electron, and each chlorine atom contributes 7 valence electrons. Therefore, the total valence electrons in the molecule is 20.

Steric number = number of lone pairs of electrons + number of atoms bonded to central atom = 2 + 4 = 6

Molecular geometry: octahedral

However, the two lone pairs of electrons on the central atom will repel the bonded pairs more than the bonded pairs will repel each other. Therefore, the shape will be bent or V-shaped.

4. SF2

Lewis structure:

F : S : F

\ /

F

The central atom (Sulfur) has 6 valence electrons, each Fluorine atom contributes 7 valence electrons. Therefore, the total valence electrons in the molecule is 20.

Steric number = number of lone pairs of electrons + number of atoms bonded to central atom = 1 + 2 = 3

Molecular geometry: trigonal planar

However, the lone pair of electrons on the central atom will repel the bonded pairs more than the bonded pairs will repel each other. Therefore, the shape will be bent or V-shaped.

5. PCl3

Lewis structure:

Cl : P : Cl

:

Cl

The central atom (Phosphorus) has 5 valence electrons, each Chlorine atom contributes 7 valence electrons. Therefore, the total valence electrons in the molecule is 26.

Steric number = number of lone pairs of electrons + number of atoms bonded to central atom = 0 + 3 = 3

Molecular geometry: trigonal planar

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Calculate the volume of 3. 00 M H2SO4 required to prepare 200. ML of 0. 200 N H2SO4. (Assume the acid is to be completely neutralized. )

Answers

Approximately 13.3 mL of 3.00 M H₂SO₄ is required to prepare 200. mL of 0.200 N H₂SO₄.

To calculate the volume of 3.00 M H₂SO₄ required to prepare 200. mL of 0.200 N H₂SO₄, we can use the formula for molarity:

Molarity (M) = moles of solute / volume of solution in liters

We can rearrange this formula to solve for volume:

Volume (in liters) = moles of solute / molarity

First, let's calculate the moles of H₂SO₄ in 200. mL of 0.200 N solution:

0.200 N = 0.200 mol/L

Moles of H₂SO₄ = 0.200 mol/L x 0.200 L = 0.0400 mol

Next, we can use this value and the concentration of the 3.00 M H₂SO₄ to calculate the volume of the concentrated acid needed:

Volume = moles of solute / molarity

Volume = 0.0400 mol / 3.00 mol/L

Volume = 0.0133 L or 13.3 mL

So, to make 200 mL of 0.200 N H₂SO₄ , roughly 13.3 mL of 3.00 M H₂SO₄  is required.

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If a piece of cadmium with mass 65.6 g at a temperature of 100.0°C is dropped into 25.0 g of water at 23.0°C the final temperature is 32.7°C. What is the specific heat capacity of cadmium?

Answers

To calculate the specific heat capacity of cadmium, we can use the formula:

Q = mcΔT, Where Q is the heat transfer, m is the mass, c is the specific heat capacity, and ΔT is the change in temperature. Since the heat gained by the water equals the heat lost by the cadmium, we can set up the following equation:
mc_cadmium (Tfinal - Tinitial_cadmium) = mc_water (Tfinal - Tinitial_water).

Given:
m_cadmium = 65.6 g
Tinitial_cadmium = 100.0°C
m_water = 25.0 g
Tinitial_water = 23.0°C
Tfinal = 32.7°C
c_water = 4.18 J/g°C (specific heat capacity of water)

Now we can solve for c_cadmium:

65.6 * c_cadmium * (32.7 - 100.0) = 25.0 * 4.18 * (32.7 - 23.0)

Solving for c_cadmium:

c_cadmium = (25.0 * 4.18 * (32.7 - 23.0)) / (65.6 * (32.7 - 100.0))
c_cadmium ≈ 0.227 J/g°C

So the specific heat capacity of cadmium is approximately 0.227 J/g°C.

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Use the vsepr theory to predict the molecular geometry of the following molecules:
(remember, you may need to draw the lewis structure before making a prediction.)


hi


cbr4


ch2cl2


sf2


pcl3

Answers

Here are the molecular geometries for each molecule after drawing their Lewis structures:

1. HICl₄: The central I is surrounded by six electron pairs - four bonding pairs and two lone pairs. Therefore, its molecular geometry is octahedral.

2. CH₂Cl₂: The central atom C has 2 single bonds with 2 H atoms and 2 single bonds with 2 Cl atoms, with no lone pairs. The molecular geometry is also tetrahedral.

3. SF₂: The central atom S has 2 single bonds with 2 F atoms and 2 lone pairs. This gives the molecule a bent molecular geometry.

4. PCl₃: The central atom P has 3 single bonds with 3 Cl atoms and 1 lone pair. This results in a trigonal pyramidal molecular geometry.

To predict the molecular geometry using VSEPR theory, we need to first draw the Lewis structure for each molecule.

1. HICl₄:

The Lewis structure for HICl₄ is as follows:

H-I-Cl
  |
  Cl
  |
  Cl

According to VSEPR theory, the molecule has an octahedral shape. The central iodine atom is surrounded by six electron pairs - four bonding pairs and two lone pairs. The bonding pairs repel each other and try to move as far apart as possible, resulting in an octahedral shape.

2. CH₂Cl₂:


The Lewis structure for CH₂Cl₂ is as follows:

H- C - H
   |  
   Cl
   |  
   Cl

According to VSEPR theory, the molecule has a tetrahedral shape. The central carbon atom is surrounded by four electron pairs - two bonding pairs and two lone pairs. The bonding pairs repel each other and try to move as far apart as possible, resulting in a tetrahedral shape.

3. SF₂:


The Lewis structure for SF₂ is as follows:

F
|\
S--F
|/
F

According to VSEPR theory, the molecule has a bent shape. The central sulfur atom is surrounded by three electron pairs - two bonding pairs and one lone pair. The bonding pairs repel each other and try to move as far apart as possible, resulting in a bent shape.

4. PCl₃:


The Lewis structure for PCl₃ is as follows:

Cl
  |
Cl - P - Cl
  |

According to VSEPR theory, the molecule has a trigonal pyramidal shape. The central phosphorus atom is surrounded by four electron pairs - three bonding pairs and one lone pair. The bonding pairs repel each other and try to move as far apart as possible, resulting in a trigonal pyramidal shape.

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1. 98 g of calcium chloride and 3. 75 g of sodium oxide are combined. Theoretically,


what mass of solid product could be formed from these amounts of reactants? What


is the limiting reactant?

Answers

Based on the stoichiometry, sodium oxide is the limiting reactant because it produces less product compared to the calcium chloride. Therefore, 0.998 g of calcium oxide is the maximum amount of product that can be formed.

To determine the theoretically possible mass of solid product and the limiting reactant, we need to first write the balanced chemical equation for the reaction between calcium chloride and sodium oxide:

[tex]CaCl2 + Na2O → CaO + 2NaCl[/tex]

The stoichiometric ratio of calcium chloride to sodium oxide in the equation is 1:1, which means that for every 1 mole of calcium chloride that reacts, 1 mole of sodium oxide is required. We can use this ratio to calculate the moles of each reactant:

moles of [tex]CaCl2[/tex] = 1.98 g / 110.98 g/mol = 0.0178 mol

moles of [tex]Na2O[/tex] = 3.75 g / 61.98 g/mol = 0.0604 mol

According to the balanced equation, for every mole of calcium chloride that reacts, 1 mole of calcium oxide is produced. Therefore, the theoretical yield of calcium oxide can be calculated based on the moles of calcium chloride:

moles of [tex]CaO[/tex] = 0.0178 mol

mass of [tex]CaO[/tex] = moles of[tex]CaO[/tex] x molar mass of [tex]CaO[/tex]

mass of [tex]CaO[/tex] = 0.0178 mol x 56.08 g/mol

mass of [tex]CaO[/tex]= 0.998 g

Similarly, we can calculate the maximum amount of product that can be formed based on the moles of sodium oxide:

moles of [tex]NaCl[/tex]= 2 x moles of [tex]Na2O[/tex] = 0.1208 mol

mass of[tex]NaCl[/tex] = moles of [tex]NaCl[/tex] x molar mass of[tex]NaCl[/tex]

mass of [tex]NaCl[/tex]= 0.1208 mol x 58.44 g/mol

mass of [tex]NaCl[/tex] = 7.06 g

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Part B



One of the main components of an airbag is the gas that fills it. As part of the design process, you need to determine the exact amount of nitrogen that should be produced. Calculate the number of moles of nitrogen required to fill the airbag. Show your work. Assume that the nitrogen produced by the chemical reaction is at a temperature of 495°C and that nitrogen gas behaves like an ideal gas. Use this fact sheet to review the ideal gas law.



Part C



Recall the balanced chemical equation from part B of task 1:




2NaN3 → 2Na + 3N2.




Calculate the mass of sodium azide required to decompose and produce the number of moles of nitrogen you calculated in part B of this task. Refer to the periodic table to get the atomic weights

Answers

To calculate the number of moles of nitrogen required to fill the airbag, we need to use the ideal gas law.

We know the temperature of the nitrogen gas produced by the chemical reaction, which is 495°C, and we assume that it behaves like an ideal gas.

We also know the volume of the airbag, which we can use to calculate the number of moles of nitrogen using the ideal gas law equation PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature.

Once we have calculated the number of moles of nitrogen required, we can move on to part C of the question, which asks us to calculate the mass of sodium azide required to produce that amount of nitrogen.

To do this, we need to refer to the balanced chemical equation given in part B and use the atomic weights from the periodic table to calculate the mass of sodium azide needed.

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At what condition do magnesium chloride and silver nitrate react? ​

Answers

Magnesium chloride and silver nitrate react in aqueous solution when they come into contact with each other. In other words, they need to be dissolved in water for the reaction to occur. This is because both compounds are ionic and require a medium for their ions to interact and exchange. Therefore, the condition for the reaction between magnesium chloride and silver nitrate is an aqueous solution.


Magnesium chloride (MgCl₂) and silver nitrate (AgNO₃) react in an aqueous solution. The condition required for the reaction to occur is that both substances are dissolved in water. When this condition is met, a double displacement reaction takes place, leading to the formation of silver chloride (AgCl) precipitate and magnesium nitrate (Mg(NO₃)₂) in the solution. The reaction can be represented by the following balanced equation:

MgCl₂ (aq) + 2AgNO₃ (aq) → 2AgCl (s) + Mg(NO₃)₂ (aq)

1. Dissolve magnesium chloride (MgCl₂) and silver nitrate (AgNO₃) in water to create aqueous solutions.
2. Mix the two aqueous solutions together.
3. Observe the formation of silver chloride (AgCl) precipitate and magnesium nitrate (Mg(NO₃)₂) in solution as a result of the double displacement reaction.

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12. What is the weight/volume percent concentration of 100. ML of a 30. 0% (w/v) solution of


vitamin C after diluting to 200. ML?

Answers

The weight/volume percent concentration of the diluted solution is 15%.

The initial solution is a 30.0% (w/v) solution, which means that 30.0 grams of vitamin C is dissolved in 100 mL of the solution. Therefore, the amount of vitamin C in the initial solution is:

30.0% (w/v) = 30.0 g / 100 mL = 0.3 g/mL

The initial solution is then diluted to a final volume of 200 mL. Since the amount of vitamin C in the solution remains constant, we can use the following equation to calculate the final concentration:

CiVi = CfVf

where Ci and Vi are the initial concentration and volume, and Cf and Vf are the final concentration and volume.

We can rearrange the equation to solve for the final concentration:

Cf = (CiVi) / Vf

Substituting the values, we get:

Cf = (0.3 g/mL x 100 mL) / 200 mL

Cf = 0.15 g/mL

Finally, we can convert the concentration to weight/volume percent by multiplying by 100:

weight/volume percent = Cf x 100%

weight/volume percent = 0.15 g/mL x 100%

weight/volume percent = 15%

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1.85 l of a gas is collected over water at 98.0 kpa and 22.0 °c. what is the volume of the dry gas at stp?

Answers

In this problem, we are given the volume of a gas collected over water at a certain temperature and pressure. We need to determine the volume of the dry gas at STP (standard temperature and pressure).

First, we need to understand why the presence of water is important in this problem. When a gas is collected over water, some of the water vapor dissolves in the gas, which affects the volume of the gas we measure. In order to account for this, we need to use the concept of vapor pressure.

The vapor pressure of water at 22.0°C is 2.64 kPa. This means that at 22.0°C and 98.0 kPa, the total pressure is the sum of the pressure due to the gas and the pressure due to the water vapor. We can use Dalton's Law of Partial Pressures to calculate the pressure due to the gas alone:

P_gas = P_total - P_water vapor
P_gas = 98.0 kPa - 2.64 kPa
P_gas = 95.36 kPa

Now we can use the Ideal Gas Law to calculate the volume of the dry gas at STP:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature. At STP, P = 101.3 kPa and T = 273.15 K.

We can rearrange the Ideal Gas Law to solve for the volume of the dry gas:

V_dry gas = (V_collected gas * P_gas * T_STP) / (P_STP * T_collected gas)

where V_collected gas is the volume of the gas collected over water, T_collected gas is the temperature of the gas collected over water, and T_STP is the temperature at STP.

Plugging in the numbers, we get:

V_dry gas = (1.85 L * 95.36 kPa * 273.15 K) / (101.3 kPa * 295.15 K)
V_dry gas = 1.60 L

Therefore, the volume of the dry gas at STP is 1.60 L. It's important to note that the volume of the dry gas is smaller than the volume of the gas collected over water, because some of the volume was occupied by water vapor.

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What is the most crucial step during the preparation of the grignard reagent?

Answers

The most crucial step during the preparation of the Grignard reagent is ensuring that all the equipment and reactants are absolutely dry.

To ensure that the equipment and reactants are dry, the equipment must be thoroughly cleaned and dried before use, and the reactants should be purified and dried before being introduced into the reaction vessel. The solvent, typically diethyl ether, should also be dried using a drying agent such as anhydrous magnesium sulfate.

The reaction should be carried out under an inert atmosphere, such as nitrogen or argon, to prevent the formation of unwanted byproducts. By taking these precautions, the formation of the Grignard reagent can be optimized, leading to a higher yield and better quality product.

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4. 3 moles of a gas are at a temperature of 28°C with a pressure of 1. 631 atm. What volume does the gas occupy?

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The gas occupies a volume of approximately 28.18 liters at a temperature of 28°C and a pressure of 1.631 atm

To determine the volume the gas occupies at a temperature of 28°C and a pressure of 1.631 atm, we will use the Ideal Gas Law, which is defined as PV = nRT. In this equation, P represents pressure, V represents volume, n represents the number of moles of the gas, R is the ideal gas constant, and T is the temperature in Kelvin.

First, we need to convert the temperature from Celsius to Kelvin: T(K) = T(°C) + 273.15. In this case, T(K) = 28 + 273.15 = 301.15 K.

Now, we can use the Ideal Gas Law to find the volume of the gas. The ideal gas constant (R) is 0.0821 L atm/mol K. Therefore, we have:

1.631 atm (V) = 3 moles (0.0821 L atm/mol K) (301.15 K)

To find the volume (V), we can rearrange the equation and isolate V:

V = (3 moles * 0.0821 L atm/mol K * 301.15 K) / 1.631 atm

V = 45.98271 L/mol / 1.631 atm

V ≈ 28.18 L

So, the gas occupies a volume of approximately 28.18 liters at a temperature of 28°C and a pressure of 1.631 atm.

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For the same procedure described in the chemical equilibrium lab handout for determining k, 15.0 ml of organic solution was added to 71.0 ml of ki aqueous solution at 307.25 k. both the aqueous and organic solutions were prepared at 298.15 k with the apparent concentration of 0.0716 m for the i-(aq) and 0.0044 for the i2(org) solutions, respectively. after mixing these immiscible solutions, the final concentration of i2 in the organic layer was determined to be 0.00077 m through uv-vis spectroscopy. in a separate experiment, the partition coefficient was found to be k = 0.046 at 301.56k.

required:
a. determine the approximate equilibrium constant, k without making any temperature correction
b. what is the percentage enor for using the non- corrected k rather than the corrected k?

Answers

a. The equilibrium constant expression for the reaction is:

K = [I2(org)] / [I-(aq)]^2

Substituting the given values:

K = (0.00077 M) / (0.0716 M)^2

K ≈ 0.0015

b. To calculate the percent error, we need to compare the non-corrected equilibrium constant (at 307.25 K) with the corrected equilibrium constant (at 298.15 K). Using the Van 't Hoff equation, we can relate the two equilibrium constants:

ln(K2/K1) = -ΔH°/R [(1/T2) - (1/T1)]

where K1 is the equilibrium constant at temperature T1, K2 is the equilibrium constant at temperature T2, ΔH° is the standard enthalpy change for the reaction, R is the gas constant, and ln denotes the natural logarithm.

Assuming that ΔH° is approximately constant over the temperature range, we can use the experimentally determined partition coefficient at 301.56 K to estimate the enthalpy change:

ln(K2/K1) = -ΔH°/R [(1/T2) - (1/T1)]

ln(0.046/0.0015) = -ΔH°/R [(1/298.15 K) - (1/301.56 K)]

ΔH° ≈ -118 kJ/mol

Using this value of ΔH°, we can calculate the corrected equilibrium constant at 298.15 K:

ln(K2/K1) = -ΔH°/R [(1/T2) - (1/T1)]

ln(K2/0.0015) = (-118000 J/mol) / (8.314 J/mol*K) [(1/298.15 K) - (1/307.25 K)]

K2 ≈ 0.00058

The percent error is:

% Error = |(K2 - K1)/K2| x 100%

% Error = |(0.00058 - 0.0015)/0.00058| x 100%

% Error ≈ 61.5%

Therefore, using the non-corrected equilibrium constant leads to an error of approximately 61.5%.

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The elephant toothpaste reaction and the reaction of sugar and sulfuric acid are examples of

Answers

The elephant toothpaste reaction and the reaction of sugar and sulfuric acid are examples of exothermic reactions and chemical decomposition.

The elephant toothpaste reaction is a popular demonstration in which hydrogen peroxide is mixed with a catalyst, usually potassium iodide or yeast, to rapidly decompose the hydrogen peroxide into oxygen gas and water. This results in the rapid production of a large volume of foam, resembling toothpaste being squeezed from a tube. The reaction is exothermic, meaning it releases heat during the process, causing the foam to be warm or even hot to the touch.

On the other hand, the reaction between sugar (sucrose) and sulfuric acid is an example of a dehydration reaction, which is also exothermic. When concentrated sulfuric acid is added to sugar, it removes the water molecules (H2O) from the sugar, leaving behind a black mass of carbon. The reaction produces a significant amount of heat and steam, making it a visually impressive demonstration.

Both of these reactions showcase the power of chemical decomposition and the release of energy during exothermic reactions. The elephant toothpaste reaction emphasizes the rapid release of gas and foam, while the reaction between sugar and sulfuric acid highlights the process of dehydration and the production of heat.

These reactions provide insight into the various ways that chemical reactions can occur and the diverse range of outcomes that can result from different reactants and conditions.

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The period of a simple pendulum of length 1m on a massive planet is 1 sec. What is the acceleration due to gravity on that planet?

Answers

The acceleration due to gravity on the massive planet is 39.48 m/s².

How do we calculate?

The period (T) of a simple pendulum is given by:

T = 2π√(L/g),

where L is the length of the pendulum and g is the acceleration due to gravity.

In this scenario, we are given that the period of the pendulum (T) is 1 second and the length of the pendulum (L) is 1 meter.

So, substituting these values into the equation:

1 = 2π√(1/g)

Simplifying this equation :

g = (4π²) / (1²)

g = 4π² m/s²

g ≈ 39.48 m/s²

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15 moles of NaOH are dissolved in 2. 0 L of solution. What is the molarity of the solution?

Answers

The molarity of a solution is defined as the number of moles of solute dissolved in one liter of solution. To calculate the molarity of the NaOH solution, we need to divide the number of moles of NaOH by the volume of the solution in liters.

Given that 15 moles of NaOH are dissolved in 2.0 L of solution, the molarity (M) of the solution can be calculated as:

M = number of moles of solute / volume of solution in liters

M = 15 moles / 2.0 L

M = 7.5 M

Therefore, the molarity of the NaOH solution is 7.5 M.

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Can someone answer the questions in the image?.
“Balancing equations”

Answers

Ans.1

blank 1 =1

blank 2 = 3

blank 3 = 2

Ans.2

blank 1 = 6

blank 2 = 4

blank 3 = 5

Ans.

blank 1 = 11

blank 2 =  7

blank 3 = 8

complete the table below by deciding whether a precipitate forms when aqueous solutions a and b are mixed. if a precipitate will form, enter its empirical formula in the last column. solution a solution b does a precipitate form when a and b are mixed? empirical formula of precipitate potassium sulfide iron(ii) sulfate yes no zinc sulfate iron(ii) bromide yes no barium bromide potassium acetate

Answers

By considering the solubility rules, we can determine whether a precipitate will form and its empirical formula when mixing two aqueous solutions.

The table can be completed as follows(image attached):

To determine whether a precipitate will form when solutions A and B are mixed, we need to consider the solubility rules of the compounds involved. If the product of the ions in the solution is insoluble, then a precipitate will form.

In the first case, potassium sulfide (K2S) and iron(II) sulfate (FeSO4) will react to form potassium sulfate (K2SO4) and iron(II) sulfide (FeS), which is insoluble. Thus, a precipitate will form with empirical formula FeS. In the second case, both zinc sulfate (ZnSO4) and iron(II) bromide (FeBr2) are soluble in water and will not react to form an insoluble compound. Therefore, no precipitate will form.

In the third case, barium bromide (BaBr2) and potassium acetate (KC2H3O2) will react to form barium acetate (Ba(C2H3O2)2) and potassium bromide (KBr), which is soluble. However, barium acetate is insoluble and will form a precipitate with empirical formula Ba(C2H3O2)2.

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2. A Snickers bar is burned in a bomb calorimeter containing 3500 grams of water causing a


72°C temperature change. How many joules are there in a bar?

Answers

The Snickers bar released 1,077,280 joules of energy when burned.

To calculate the energy released by burning a Snickers bar, we can use the formula:

q = mcΔT

where q is the heat energy released, m is the mass of water, c is the specific heat of water, and ΔT is the temperature change.

We know the mass of water is 3500 g, and the temperature change is 72°C. The specific heat of water is 4.184 J/g°C.

Therefore:

q = (3500 g) x (4.184 J/g°C) x (72°C) = 1077280 J

So, the Snickers bar released 1,077,280 joules of energy when burned.

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A student is collecting data for the reaction of baking soda and vinegar. The initial temperature of the vinegar is 25˚ C and the final temperature of the reaction is 19˚ C. Identify the reaction as endothermic or exothermic and explain what is happening in terms of energy of the systems and the surroundings.

Answers

Answer:

According to the data supplied, the reaction of baking soda and vinegar is exothermic. Exothermic reactions transfer energy from the system to the environment, often in the form of heat. The beginning temperature of the vinegar was 25 degrees Celsius, and the ultimate temperature of the reaction was 19 degrees Celsius, indicating that heat was released into the environment. This is consistent with an exothermic process, in which energy is released and transmitted to the surroundings. As a result of the chemical interaction between baking soda and vinegar, carbon dioxide gas is created, and heat is emitted.

Which of the following describes a plant that has been exposed to a heat stimulus?


The plant loses all of its leaves.
The flower on the plant drops its petals.
The plant grows big fruit.
The plant grows tall.

Answers

A plant may go through a physiological response known as thermomorphogenesis in response to a heat stimulus. Option D.The plant grows tall. is correct.

This response may cause the plant to grow and develop in a variety of different ways, including enhanced stem elongation or modifications to the morphology of the leaves. As a result of enhanced stem elongation brought on by heat stress, plants can generally grow taller. This adaptation enables the plant to go away from the heat source and more easily absorb cooler air.

It is unusual for a plant to lose all of its leaves in response to a heat stimulation because this would mean a large loss of resources for the plant. Similar to how producing large fruit is not a usual reaction to heat stress, this is because the plant's energy resources might be diverted from reproduction to survival.

Heat stress may cause flowers to drop their petals, although this is not a universal reaction and would depend on the particular plant type and climatic factors.

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h2o is a molecular compound that is a liquid at room temperature (22 degrees celsius). this is primarily due to the fact that it has relatively what strength of intermolecular forces?

Answers

H2O, or water, is a molecular compound that is a liquid at room temperature (22 degrees Celsius). This state is primarily due to the fact that it has relatively strong intermolecular forces.

These forces are the attractive forces between the molecules of the compound, and in the case of water, these forces are called hydrogen bonds.

Hydrogen bonds are a type of dipole-dipole interaction that occurs between molecules containing a hydrogen atom bonded to a highly electronegative element, such as oxygen in water. The oxygen atom attracts the electrons in the bond, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen.

This causes an electrostatic attraction between the partially positive hydrogen atom and the partially negative oxygen atom of a neighboring water molecule.

These hydrogen bonds give water its unique properties, such as its relatively high boiling and melting points compared to other molecular compounds with similar molecular weights.

The strong intermolecular forces provided by hydrogen bonding are what make water a liquid at room temperature, as they are strong enough to hold the molecules together, but not so strong that they form a solid at this temperature.

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A soft lump of clay has water run on top of it. After a long while the water is turned off and allowed to dry. There is no clay left; instead there are small pebbles and other types of components left on the table. Which natural process is this modeling?



A. Erosion



B. Deposition



C. Chemical weathering



D. Physical weathering

Answers

The natural process being modeled here is "Chemical weathering". The correct answer is option c.

Chemical weathering is the process by which rocks and minerals are broken down through chemical reactions with water, air, and other substances.

In this case, the clay is being broken down by the water, which is dissolving some of the minerals in the clay and carrying them away. As the water evaporates, the minerals are left behind, forming small pebbles and other components.

This process may occur over a long period of time, depending on the type of clay and the amount of water present. Chemical weathering is an important part of the Earth's natural processes, as it helps to shape the landscape and produce new materials that can be used for building and other purposes.

The correct answer is option c.

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During the combustion of propane(C3H8), 197. 4 grams of oxygen gas is consumed. How much water vapor is produced as a result?

Answers

197.4 grams of oxygen gas is consumed during the combustion of propane. Using stoichiometry, it is calculated that 88.43 grams of water vapor is produced as a result.

The balanced chemical equation for the combustion of propane is:

C₃H₈ + 5O₂ → 3CO₂ + 4H₂O

From the equation, we can see that for every mole of propane (C₃H₈) consumed, 4 moles of water (H₂O) are produced.

To solve the problem, we need to first find the number of moles of oxygen (O₂) consumed:

Moles of O₂ = Mass of O₂ / Molar mass of O₂

Molar mass of O₂ = 32 g/mol (from the periodic table)

Moles of O₂ = 197.4 g / 32 g/mol

Moles of O₂ = 6.16875 mol

Since the balanced chemical equation shows that 5 moles of O₂ are required for every mole of C₃H₈, we can find the number of moles of C₃H₈ consumed:

Moles of C₃H₈ = Moles of O₂ / 5

Moles of C₃H₈ = 6.16875 mol / 5

Moles of C₃H₈ = 1.23375 mol

Now, we can find the number of moles of H₂O produced:

Moles of H₂O = Moles of C₃H₈ x 4

Moles of H₂O = 1.23375 mol x 4

Moles of H₂O = 4.935 mol

Finally, we can find the mass of H₂O produced:

Mass of H₂O = Moles of H₂O x Molar mass of H₂O

Molar mass of H₂O = 18 g/mol (from the periodic table)

Mass of H₂O = 4.935 mol x 18 g/mol

Mass of H₂O = 88.43 g

Therefore, 88.43 grams of water vapor is produced as a result of the combustion of propane with 197.4 grams of oxygen gas.

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