Given that benzaldehyde is a meta- director, in the same Marvin editor draw all three resonance structures for the carbocation intermediate that results from STEP 2 in the electrophilic aromatic substitution reaction when benzaldehyde reacts with Br2 in the presence of FeBr3. If you do not remember the structure of the benzene derivative, consult the L3 complete lecture notes slides #21 - 24.

Answers

Answer 1

Answer:

The reaction of FeBr3/Br2 with benzaldehyde will yield a major product in which the -Br is attached to the benzaldehyde at the meta position.

Explanation:

In chemistry, resonance is a way of describing bonding in certain molecules or ions by the combination of several contributing structures into a resonance hybrid in valence bond theory. Resonance structures often explain the formation of certain major and minor products in organic chemistry reactions.

Aromatic aldehydes and ketones undergo electrophilic substitution reactions such as nitration, sulphonation and halogenation. Since the aldehydic group (-CHO) and ketonic group (-COR or -COAr) are electron-withdrawing, they are deactivating and m-directing.

In benzaldehyde, the ring becomes deactivated at ortho & para positions due to an electron withdrawing aldehyde group. Hence electrophilic substitution is favored at Meta position.

This implies that the reaction of FeBr3/Br2 with benzaldehyde will yield a major product in which the -Br is attached to the benzaldehyde at the meta position.

Given That Benzaldehyde Is A Meta- Director, In The Same Marvin Editor Draw All Three Resonance Structures

Related Questions

Classify each amino acid according to whether its side chain is predominantly protonated or deprotonated at a pH of 7.40. The pKa values of the Asp, His, and Lys side chains are 3.65, 6.00, and 10.53, respectively.

Answers

Answer and Explanation:

7.40 becomes lower or shorter than the pKa of functional groups or chains of all the 3 amino acids respectively Lys, His, as well as Asp, although since pH provided throughout the statement. However, all of the covalent chains or bonds of the three compounds or acids (amino) will serve a purpose in the pro-toned pattern.

The pH during which everyone's binding sites will mostly keep track of customer for someone's comparison is:

Lys:

[tex]pH > 10.53[/tex]

His:

[tex]pH > 6.00[/tex]

Asp:

[tex]pH > 3.65[/tex]

A 38.8 gram piece of metal absorbs 181J as it temperature increases from 25.0 degree celsius to 36.0 degree celsius. What is the specific heat of the metal?


__________________________J/g degree C

Answers

Answer: 0.424 J/g°C

Explanation:

For this problem, we would have to manipulate the equaiton for heat, q=mCT. Specific heat is the C in the equation. Since we are looking for specific heat, we manipulate the equation so that it says C=.

[tex]C=\frac{q}{m(deltaT)}[/tex]

*I didn't know how to type in delta so I just wrote the word delta, but pretend you see a Δ.

Now that we have our equation, we can plug in our values and solve.

[tex]C=\frac{181J}{(38.8g)(36-25°C)}[/tex]

*Please ignore the capital A in the equation. It pops up every time I type in the ° sign.

[tex]C=0.424J/g°C[/tex]

A 1.34 mole sample of LiCl dissolves in water, The volume of the final
solution is 0.86L. Find the Molarity of the Solution.​

Answers

Answer:

[tex]1.56 \,\,mol/L[/tex]

Explanation:

Molarity of the solution measures number of moles of a solute per litre of solution.

Molarity = volume of solution in litres/number of moles of solute dissolved in solution

Volume of solution in litres = 0.86 L

Also, 1.34 mole sample of LiCl dissolves in water

So,

Molarity of the Solution = [tex]\frac{1.34}{0.86}=1.56 \,\,mol/L[/tex]

Draw the reaction mechanism the reaction between 2-methylpent-2-ene and chlorine. State the type of reaction. Label the electrophile, intermediate and final product.​

Answers

Answer:

Explanation:

CH₃C(CH₃)=CH-CH₂-CH₃ ( 2 - methylpent-2-ene)

Cl₂ ⇒ Cl⁺ + Cl⁻

Cl⁺( electrophile)

CH₃C(CH₃)=CH-CH₂-CH₃  + Cl⁺ ( electrophile)  ⇒ CH₃C⁺(CH₃)-C(Cl)H-CH₂-CH₃ (  intermediate )

CH₃C⁺(CH₃)-C(Cl)H-CH₂-CH₃ + Cl⁻  ⇒ CH₃CCl(CH₃)-C(Cl)H-CH₂-CH₃ ( final product )

It is electrophilic addition reaction.

How many moles of NaOH will be required to produce 375.4 g of any Na2S04

Answers

Answer:

5.28 moles of NaOH.

Explanation:

Step 1:

Determination of the number of mole in

375.4 g of any Na2S04.

Molar mass of Na2SO4 = (2x23) + 32 + (16x4) = 142g

Mass of Na2SO4 = 375.4g

Number of mole of Na2SO4 =..?

Mole = Mass /Molar Mass

Number of mole of Na2SO4 = 375.4/142 = 2.64 moles

Step 2:

The balanced equation for the reaction.

H2SO4 + 2NaOH —> Na2SO4 + 2H2O

Step 3:

Determination of the number of mole of NaOH needed for the reaction.

From the balanced equation above,

2 moles of NaOH reacted to produce 1 mole of Na2SO4.

Therefore, Xmol of NaOH will react to produce 2.64 moles of Na2SO4 i.e

Xmol of NaOH = 2 x 2.64

Xmol of NaOH = 5.28 moles

Therefore, 5.28 moles of NaOH is needed for the reaction.

A solution consists of 0.27 M MgCl2 and 0.7 M CuCl2. Calculate the concentration of hydroxide ion needed to separate the metal ions. The Ksp of Mg(OH)2 is 6.3x10-10, and the Ksp of Cu(OH)2 is 2.2x10-20. Multiply your answer by 106 and enter that number to 2 decimal places.

Answers

Answer:

The concentration of hydroxide ion needed to precipitate Cu²⁺ whereas Mg²⁺ still in solution is 1.77x10⁻¹⁰

Explanation:

Based on the different Ksp of the hydroxides of the metal ions it is possible to precipitate 1 metal as hydroxide whereas the other still in solution.

Ksp of both hydroxides is:

Mg(OH)₂ ⇄ Mg²⁺ + 2OH⁻

Ksp = [Mg²⁺] [OH⁻]² = 6.3x10⁻¹⁰

Cu(OH)₂ ⇄ Cu²⁺ + 2OH⁻

Ksp = [Cu²⁺] [OH⁻]² = 2.2x10⁻²⁰

Replacing with the concentration of the metals:

[0.27] [OH⁻]² = 6.3x10⁻¹⁰

[OH⁻] = 4.83x10⁻⁵M

That means the precipitation of Mg²⁺ begins when [OH⁻] is 4.83x10⁻⁵M

[0.7] [OH⁻]² = 2.2x10⁻²⁰

[OH⁻] = 1.77x10⁻¹⁰

As the Cu²⁺ needs a low concentration of OH⁻ to begin precipitation,

the concentration of hydroxide ion needed to precipitate Cu²⁺ whereas Mg²⁺ still in solution is 1.77x10⁻¹⁰

Calculate ΔHrxnΔHrxn for the following reaction: CH4(g)+2O2(g)→CO2(g)+2H2O(l)CH4(g)+2O2(g)→CO2(g)+2H2O(l) Use the following reactions and given ΔHΔH values. CH4(g)+O2(g)→CH2O(g)+H2O(g)CH4(g)+O2(g)→CH2O(g)+H2O(g), ΔH=−ΔH=−284 kJkJ CH2O(g)+O2(g)→CO2(g)+H2O(g)CH2O(g)+O2(g)→CO2(g)+H2O(g), ΔH=−ΔH=−527 kJkJ H2O(l)→H2O(g)H2O(l)→H2O(g), ΔH=ΔH= 44.0 kJ

Answers

Answer: the enthalpy of reaction is, -155 kJ

Explanation:-

According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

The final reaction is:

[tex]CH_4(g)+2O_2(g)\rightarrow CO_2(g)+2H_2O(l)[/tex]    [tex]\Delta H_{rxn}=?[/tex]

The intermediate balanced chemical reaction will be,

(1) [tex]CH_4(g)+O_2(g)\rightarrow CH_2O(g)+H_2O(g)[/tex]     [tex]\Delta H_1=-284kJ[/tex]

(2) [tex]CH_2O(g)+O_2(g)\rightarrow CO_2(g)+H_2O(g)[/tex]    [tex]\Delta H_2=-527kJ[/tex]

(3) [tex]H_2O(l)\rightarrow H_2O(g)[/tex]    [tex]\Delta H_3=44.0kJ[/tex]

Now multiplying (3) by 2 and adding all the equations, we get :

[tex]\Delta H_{rxn}=\Delta H_1+\Delta H_2+2\times \Delta H_3[/tex]

[tex]\Delta H_{rxn}=(-284)+(-527)+2\times (44)[/tex]

[tex]\Delta H_{rxn}=-155kJ[/tex]

Therefore, the enthalpy of reaction is, -155 kJ

Consider the experimental data for multiple experiments with different pressures and volumes of gases.
Experiment PV Value (Pa-mL)
1 1.10 x 106
2 1.14 x 106
3 1.18 x 106
4 1.16 x 106
5 1.19 x 106
Boyle's law that pressure and volume are inversely related because___________.

Answers

Answer: Boyle's law states that pressure and volume are inversely related because the product of pressure and volume is approximately constant.

Explanation:

In each of the given values product of P and V, that is, PV remains constant. As according to Boyle's law, at constant temperature the pressure will be inversely proportional to volume of the gas.

Mathematically,    [tex]P \propto \frac{1}{V}[/tex]

or,            PV = k

where,   k = Proportionality constant

              P = pressure of gas

              V = volume of gas

Product of values will only remain constant when pressure is inversely proportional to volume.

Therefore, we can conclude that Boyle's law states that pressure and volume are inversely related because the product of pressure and volume is approximately constant.

Boyle's law mentioned that pressure and volume should be inversely related since the product of pressure and volume is approximately constant.

Boyle's law

According to this law, at a constant temperature, the pressure should be inversely proportional to the volume of the gas.

PV = k

Here

k = Proportionality constant

P = Pressure

V = volume of gas

So based on this we can conclude that Boyle's law mentioned that pressure and volume should be inversely related since the product of pressure and volume is approximately constant.

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PLEAS HELP I HAVE LIMITED TIME!!
Which compound is the limiting reagent?
Select one:
O2
O H20
H2
Cannot be determined.

Answers

Answer:

H2 is the limiting reactant.

Explanation:

From the diagram above:

H2 => White ball

O2 => Red ball

Before the reaction

H2 => White ball => 10

O2 => Red ball => 7

After the reaction

H2O => White and red ball => 10

O2 => 2

From the simple illustration above, we can see that all the H2 were used up in the reaction but there are left over of O2.

This simply means that H2 is the limiting reactant as all of it is used up in the reaction while O2 is the excess reactant as there are leftover.

Steam reforming of methane (CH4 ) produces "synthesis gas," a mixture of carbon monoxide gas and hydrogen gas, which is the starting point for many important industrial chemical syntheses. An industrial chemist studying this reaction fills a tank with of methane gas and of water vapor, and when the mixture has come to equilibrium measures the amount of carbon monoxide gas to be 18 mol . Calculate the concentration equilibrium constant for the steam reforming of methane at the final temperature of the mixture. Round your answer to significant digits.

Answers

The question is incomplete, here is the complete question:

Steam reforming of methane [tex](CH_4)[/tex] produces "synthesis gas," a mixture of carbon monoxide gas and hydrogen gas, which is the starting point for many important industrial chemical syntheses. An industrial chemist studying this reaction fills a 125 L tank with 20 mol of methane gas and 10 mol of water vapor at 38 degrees celsius. He then raises the temperature, and when the mixture has come to equilibrium measures the amount of hydrogen gas to be 18 mol . Calculate the concentration equilibrium constant for the steam reforming of methane at the final temperature of the mixture. Round your answer to significant digits.

Answer: The equilibrium constant for the reaction is [tex]3.99\times 10^{-2}[/tex]

Explanation:

We are given:

Initial moles of methane gas = 20 moles

Initial moles of water vapor = 10 moles

Equilibrium moles of carbon monoxide = 18 moles

Volume of the tank = 125 L

The chemical equation for the reaction of methane and water vapor follows:

                       [tex]CH_4(g)+H_2O(g)\rightleftharpoons CO(g)+3H_2(g)[/tex]

Initial:                20             10

At eqllm:          20-x         10-x            x            3x

Evaluating the value of 'x':

[tex]\Rightarrow 3x=18\\x=6[/tex]

So, equilibrium moles of methane gas = (20 - x) = [20 - 6] = 14 mol

Equilibrium moles of water vapor = (10 - x) = [10 - 6] = 4 mol

Equilibrium moles of carbon monoxide gas = x = 6 mol

The expression of equilibrium constant for the above reaction follows:

[tex]K_{eq}=\frac{[H_2]^3[CO]}{[CH_4][H_2O]}[/tex]

We are given:

[tex][H_2]=\frac{18}{125}=0.144M[/tex]

[tex][CO]=\frac{6}{125}=0.048M[/tex]

[tex][CH_4]=\frac{14}{125}=0.112M[/tex]

[tex][H_2O]=\frac{4}{125}=0.032M[/tex]

Putting values in above expression, we get:

[tex]K_{eq}=\frac{(0.144)^3\times 0.048}{0.112\times 0.032}\\\\K_{eq}=3.99\times 10^{-2}[/tex]

Hence, the equilibrium constant for the reaction is [tex]3.99\times 10^{-2}[/tex]

Classify each titration curve as representing a strong acid titrated with a strong base, a strong base titrated with a strong acid, a weak acid titrated with a strong base, a weak base titrated with a strong acid, or a polyprotic acid titrated with a strong base. A. Strong acid/ strong base.B. Strong base/ strong acid.C. Weak acid/ strong base.D. Weak base/ strong acid.E. Polyprotic acid/ strong base.

Answers

Answer:

Acid base titration curves shows the pH at equivalence point

Explanation:

Since the images were not shown, I will proceed to give a general description of the following acid-base titration curves:

In a strong acid-strong base titration, the acid and base will react to form a neutral solution. At the equivalence point of the reaction, hydronium (H+) and hydroxide (OH-) ions will react to form water, leading to a pH of 7.

The titration curve reflects the strengths of the corresponding acid and base. If one reagent is a weak acid or base and the other is a strong acid or base, the titration curve is irregular, and the pH shifts less with small additions of titrant near the equivalence point.

Polyprotic acids are able to donate more than one proton per acid molecule, in contrast to monoprotic acids that only donate one proton per molecule. In the titration curve of a polyptotic acid and a strong base, The curve starts at a higher pH than a titration curve of a strong base. There is always a steep climb in pH before the first midpoint. Gradually, the pH increases until it passes the midpoint; Right before the equivalence point there is a very sharp increase in pH.

Answer:

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Explanation:

Aqueous solutions of barium chloride and silver nitrate are mixed to form solid silver chloride and aqueous barium nitrate. The complete ionic equation contains which of the following species (when balanced in standard form)?
A. NO (aq)
B. 2Ba (aq)
C. 2Ag (aq)
D. CI(aq)

Answers

Answer:

Option C

Explanation:

Consider the ionic equation of this chemical equation. We are given barium chloride and silver nitrate as the reactants, and silver chloride and barium nitrate as the products. We can thus conclude that the ionic equation ( not balanced yet ) should be as follows -

Ba( 2 + ) + Cl ( - ) + Ag ( + ) + NO3 ( - ) ------> AgCl + Ba( 2 + ) + NO3( - )

As you can see these compounds are present in aqueous solutions, and are thus dissociated.

______________________________________________________

Now let us take a look at the number of elements on the reactant and product sides, and balance this chemical equation out -

Ba( 2 + ) + 2Cl ( - ) + 2Ag ( + ) + 2NO3 ( - ) ------> 2AgCl + Ba( 2 + ) + 2NO3( - )

Solution = Option C!

A 1.8 g mass of fructose is added to 0.100 kg of water and it is
found that the freezing point has decreased by 0.186 °C. Given
that the Kf value of water is 1.86 °C kg/mol, what is the molar
mass of fructose (van't Hoff factor, i = 1)?
g/mol
Round your answer to the nearest whole number. Do not include units in your answer​

Answers

The molar mass of fructose will be "180 g/mol". To understand the calculation check below.

Molar mass and Molality

According to the question,

Fructose mass = 1.8 g

Water's mass = 0.100 kg

Molal freezing point depression constant, [tex]K_f[/tex] = 1.86°C/m

Freezing point change, Δ[tex]T_f[/tex] = 0.186°C

Freezing point constant, [tex]K_f[/tex] = 1.86°C/m

We know the relation,

→ Δ[tex]T_f[/tex] = i × [tex]K_f[/tex] × m

or,

         = i × [tex]K_f[/tex] × [tex]\frac{Fructose \ mass}{Fructose \ molar \ mass\times Solvent's \ mass}[/tex]

By substituting the values, we get

0.186 = 1 × 1.86 × [tex]\frac{1.8}{Fructose \ molar \ mass\times 0.100}[/tex]

By applying cross-multiplication,

Molar mass = 180 g/mol

Thus the above approach is right.          

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A 1.8 g mass of fructose is added to 0.100 kg of water and it is found that the freezing point has decreased by 0.186 °C. The molar mass of fructose is 180 g/mol.

Given:

ΔTf = 0.186 °C

Kf = 1.86 °C kg/mol

m = mass of fructose/mass of water

mass of fructose = 1.8 g

mass of water = 0.100 kg = 100 g

Use the equation:

ΔTf = Kf mi

Where:

ΔTf is the change in freezing point (in °C)

Kf is the cryoscopic constant of water (in °C kg/mol)

m is the molality of the solute (in mol/kg)

i is the van't Hoff factor

m = (mass of fructose) / (mass of water)

m = 1.8 g / 100 g

m = 0.018 mol/kg

Rearrange the equation to solve for the molar mass (M):

ΔTf = Kfmi

Substitute the values in the above equation:

0.186 = 1.86 × 0.018 × 1 / M

By applying cross multiplication,

Molar mass (M) = 180 g/mol

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Question 5 Tungsten is a solid phase of tungsten still unknown to science. The only difference between it and ordinary tungsten is that Tungsten forms a crystal with an fcc unit cell and a lattice constant . Calculate the density of Tungsten .

Answers

Complete Question

The complete question is shown on the first uploaded image  

Answer:

The density is  [tex]\rho = 21.1 \ g/cm^3[/tex]

Explanation:

From the question we are told that

      The lattice constant is  [tex]a = 0.387 nm = 0.387 *10^{-9} \ m[/tex]

Generally the volume of the unit cell is  [tex]V = a^3[/tex]

                                                             =>   [tex]V = [0.387 *10^{-9}]^2[/tex]

                                                                   [tex]V = 5.796 *10^{-29} \ m^3[/tex]

Converting to  [tex]cm^3[/tex]   We have  [tex]5.796 *10^{-29} * 1000000 = 5.796 *10^{-23} cm^3[/tex]

The molar mass of Tungsten is constant with a value  [tex]Z = 184 g/mol[/tex]

One mole of Tungsten contains  [tex]6.022*10^{23}[/tex] unit cells

    Where [tex]6.022*10^{23}[/tex]  is  a constant for the number of atom in one mole of a substance(Tungsten) which is known as Avogadro's constant

      Now for FCC distance  the number of atom per unit cell  is  n =  4

               Mass of Tungsten (M) =  [tex]= \frac{Z * n }{1 \ mole \ of \ Tungsten}[/tex]

=>              Mass of Tungsten (M) =  [tex]= \frac{184 * 4 }{6.023*10^{23}}[/tex]

=>              Mass of Tungsten (M) =  [tex]= 1.222*10^{-21} \ g[/tex]

 Now  

      The density of  Tungsten is  

                  [tex]\rho = \frac{M}{V}[/tex]

substituting values

                [tex]\rho = \frac{1.222*10^{-21}}{5.796*10^{-23}}[/tex]

                [tex]\rho = 21.1 \ g/cm^3[/tex]

               

                   

If 200 mL of 3M CaCO3 is diluted to 250 mL, what is the new molarity?

Answers

Answer: The new molarity is 2.4 M

Explanation:

According to the dilution law,

[tex]C_1V_1=C_2V_2[/tex]

where,

[tex]C_1[/tex] = concentration of pure solution = 3 M

[tex]V_1[/tex] = volume of pure solution = 200 ml

[tex]C_2[/tex] = concentration of diluted solution= ?

[tex]V_2[/tex] = volume of diluted solution= 250 ml

Putting in the values:

[tex]3M\times 200ml=M_2\times 250ml[/tex]

[tex]M_2=2.4M[/tex]

Thus the new molarity is 2.4 M

Amylose is a "polysaccharide" that plants use to store energy. It is made of repeating subunits of C6H10O5. If a particular amylose molecule has 2537 of these subunits, what is its molecular formula? What is its molar mass? What is the empirical formula of amylose?

Answers

Answer:

See exaplanation

Explanation:

For this question, we several sub-questions, lets start with the first one:

What is its molecular formula?

For this question we have to multiply the subunit by the number of subunits in the polysaccharide, so:

[tex](C_6H_1_0O_5)*2537=C_1_5_2_2_2H_2_5_3_7_0O_1_2_6_8_5[/tex]

What is its molar mass?

For this question, we have to find the molar mass of 1 subunit and then multiply by the number of subunits:

Atomic masses: C: 12 g/mol H: 1 g/mol O: 16 g/mol

Now we can multiply, the atomic masses by the number of atoms, so:

[tex](12*6)+(10*1)+(16*5)=~162~g/mol[/tex]

If we take into account the number of subunits:

[tex](162~g/mol)*2537=410994~g/mol[/tex]

What is the empirical formula of amylose?

In this case, we have to remember that the empirical formula is the smallest number of atoms. In other words, we have to simplify the formula. Therefore, the smallest formula is the subunit formula: [tex]C_6H_1_0O_5[/tex].

I hope it helps

A metal M react with sulphur ro form MS. If 3.6g of M reacts with 0.09mol of sulphur to form MS . what is the name of M.

Answers

Answer:

Calcium

Explanation:

We must first put down the reaction equation as this will serve as a guide in solving the question.

M(s) + S(s) -----> MS(s)

According to the reaction equation; 1 mole of metal reacts with 1 mole of sulphur. Hence 0.09 moles of sulphur reacts with 0.09 moles of metal.

Now recall that;

Number of moles (n) = mass(m)/ molar mass(M)

Since

mass of metal reacted= 3.6g

Number of moles of metal= 0.09 moles

Then;

Making molar mass of metal the subject of the formula;

Molar mass of metal = mass of metal / number of moles of metal

Molar mass of metal = 3.6g /0.09 moles

Molar mass of metal= 40 gmol-1

The metal having a molar mass of 40gmol-1 is calcium, therefore the metal is calcium.

A 1424 gram sample of a liquid at an initial temperature of 30.0 degrees C absorbs 1560 J of heat. Given the specific heat of 2.44 J/g degree C, what is the final temperature of the liquid?


____________________ degree C

Answers

Answer:

THE FINAL TEMPERATURE OF THE LIQUID SAMPLE  IS 30.45 DEGREE CELSIUS

Explanation:

Mass of the liquid sample = 1424 g

Initail temperature = 30 degree C

Heat evolved = 1560 J

Specific heat of the liquid = 2.44 J/g degree C

Final temperature = unknown

Since the heat evolved by a substance is the product of the mass, specific heat capacity and the change in temperature of the sample

Heat = Mass * Specific heat * change in temp.

                                       H = m c (T2-T1)

Re-arranging the formula by making T2 (final temperature) the subject of the equation, we have:

         T2= H/ m c + T1

So therefore, introducing the value of the variables and solving for T2, we have:

T2 = 1560 / 1424 * 2.44 + 30

T2 = 1560 / 3474.56 + 30

T2 = 0.4487 + 30

T2 = 30.4487 degree C

The final temperature of the liquid sample is approximately 30.45 degree C

Which type of semiconductor is created by doping with atoms that contain more valence electrons than the semiconductor material ?

Answers

Answer:

N-Type Semiconductor

Explanation:

Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all lone pairs of electrons. Show the formal charges of all atoms in the correct structure. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom for:SeO2 and CO2?3

Answers

Answer:

See explanation below

Explanation:

In this case, let's see both molecules per separate:

In the case of SeO₂ the central atom would be the Se. The Se has oxidation states of 2+, and 4+. In this molecule it's working with the 4+, while oxygen is working with the 2- state. Now, how do we know that Se is working with that state?, simply, let's do an equation for it. We know that this molecule has a formal charge of 0, so:

Se = x

O = -2

x + (-2)*2 = 0

x - 4 = 0

x = +4.

Therefore, Selenium is working with +4 state, the only way to bond this molecule is with a covalent bond, and in the case of the oxygen will be with double bond. See picture below.

In the case of CO₂ happens something similar. Carbon is working with +4 state, so in order to stabilize the charges, it has to be bonded with double bonds with both oxygens. The picture below shows.

Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constant (g) (g) (g) (g) (g) (g) Suppose also ≫. That is, the first step is much faster than the second.

Write the balanced chemical equation for the overall chemical reaction:
Write the experimentally-observable rate law for the overall chemical reaction.

Note: your answer should not contain the concentrations of any intermediates.

Answers

Answer:

Koverall [NO]^2 [Br2]

Balanced chemical reaction equation;

2NO + Br2 ⇄2NOBr

Explanation:

Consider the first step in the reaction;

NO(g) + Br2(g) ⇄ NOBr2(g) fast

The second step is the slower rate determining step

NOBr2(g) + NO(g) ⇄ 2NOBr(g)

Given that k1= [NOBr2]/[NO] [Br2]

k2= [NOBr2] [NO]

The concentration of the intermediate is now;

[NOBr2]= k1[NO][Br2]

It then follows that overall rate of reaction is

Rate= k1k2[NO]^2 [Br2]

Since k1k2=Koverall

Rate= Koverall [NO]^2 [Br2]

Answer:

NOBr_2(g)+NO(g)----> 2NOBr(g)

Explanation:

Answer retrieved from ALEKS

Draw a mechanism for the reaction of methylamine with 2-methylpropanoic acid. Draw any necessary curved arrows. Show the products of the reaction. Include any nonzero formal charges and all lone pairs of electrons. Indicate which side of the reaction is favored at equilibrium.

Answers

Answer:

See figure 1

Explanation:

On this case we have a base (methylamine) and an acid (2-methyl propanoic acid). When we have an acid and a base an acid-base reaction will take place, on this specific case we will produce an ammonium carboxylate salt.

Now the question is: ¿These compounds can react by a nucleophile acyl substitution reaction? in other words ¿These compounds can produce an amide?

Due to the nature of the compounds (base and acid), the nucleophile (methylamine) doesn't have the ability to attack the carbon of the carbonyl group due to his basicity. The methylamine will react with the acid-producing a positive charge on the nitrogen and with this charge, the methylamine loses all his nucleophilicity.

I hope it helps!

When I was a boy, Uncle Wilbur let me watch as he analyzed the iron content of runoff from his banana ranch. A 25.0-mL sample was acidified with nitric acid and treated with excess KSCN to form a red complex. (KSCN itself is colorless.) The solution was then diluted to 100.0 mL and put in a variable-path length cell. For comparison, a 10.0-mL reference sample of 6.74 times 10^-4 M Fe^3+ was treated with HNO_3 and KSCN and diluted to 50.0 mL, The reference was placed in a cell with a 1.00-cm light path. The runoff sample exhibited the same absorbance as the reference when the path length of the runoff cell was 2.41 cm. What was the concentration of iron in Uncle Wilbur's runoff?

Answers

Answer:

C = 2.24x10⁻⁴ M

Explanation:

The concentration of iron in Uncle Wilbur's runoff can be calculated using Beer-Lambert law:

[tex] A = \epsilon*C*l [/tex]   (1)

Where:

A: is the absorbance of the compound

ε: is the molar absorptivity of the compound

C: is the concentration of the compound

l: is the optical path length

Since the runoff sample exhibited the same absorbance as the reference sample, we can find the concentration using equation (1):      

[tex] \epsilon*C_{1}*l_{1} = \epsilon*C_{2}*l_{2} [/tex]    (2)

Where:

Subscripst 1 and 2 refer to Uncle Wilbur's runoff and to reference sample, respectively.

l₁ = 2.41 cm

l₂ = 1.00 cm

We can find C₂ as follows:

[tex] C_{2} = \frac{C_{2i}*V_{i}}{V_{f}} [/tex]    (3)

Where:

[tex]C_{2i}[/tex]: is the initial concentration of the reference sample = 6.74x10⁻⁴ M

[tex]V_{i}[/tex]: is the initial volume = 10.0 mL

[tex]V_{f}[/tex]: is the final volume = 50.0 mL

[tex] C_{2} = \frac{6.74 \cdot 10^{-4} M*10.0 mL}{50.0 mL} = 1.35 \cdot 10^{-4} M [/tex]

Now, we can find C₁ using equation (2):

[tex] C_{1} = \frac{C_{2}*l_{2}}{l_{1}} = \frac{1.35 \cdot 10^{-4} M*1.00 cm}{2.41 cm} = 5.60 \cdot 10^{-5} M [/tex]

Finally, since the runoff solution was diluted to 100.0 mL, the initial concentration can be calculated using equation (3) for [tex]C_{1i}[/tex]:

[tex]C_{1i} = \frac{C_{1}*V_{f}}{V_{i}} = \frac{5.60 \cdot 10^{-5} M*100.0 mL}{25.0 mL} = 2.24 \cdot 10^{-4} M[/tex]

Therefore, the concentration of iron in Uncle Wilbur's runoff is 2.24x10⁻⁴ M.

I hope it helps you!

Write condensed and bond-line structural formulas for all of the constitutional isomers Practice problem 4.1 with the molecular formula C7H16. (There are a total of nine constitutional isomers.)

Answers

Answer:

See figure 1.

Explanation:

In this case have to take into account that all structures must have the formula: [tex]C_7H_16[/tex]. If we remember the general formula for alkanes: [tex]C_nH_2_n_+_2[/tex] if we have "7" carbons (n=7) we will have 16 hydrogens.  Therefore all the structures that fit with this formula are alkanes.

Which is the best method for collection of co2

Answers

Answer:

The best way is to burn fuel with oxygen instead of air

Consider four beakers labeled A, B, C, and D, each containing an aqueous solution and a solid piece of metal. Identity the beakers in which a chemical reaction will occur and those in which no reaction will occur. Drag each item to the correct bin.
1. Mn(s) Ca(NO3)2(aq)
2. KOH(aq) Fe(s)
3. Pt(NO3)2(aq) Cu(s)
4. Cr(s) H2SO4(aq)
A. Reaction
B. Non-reaction
Consider the following data for five hypothetical element: Q, W, X, Y, and Z. Rank the elements from most reactive to least reactive.
Combination Observation of reaction
Q + W+ Reaction occurs
X + Z+ No reaction
W + Z+ Reaction occurs
Q+ + Y Reaction occurs
Place the element symbol from most to least reactive.
1. Q
2. W
3. X
4. Y
5. Z
A. Most reactive
B. Least reactive
Use the following reactions to arrange the elements A, B, C, and D in order of their rodox reactivity from most reactive to least reactive. Rank from most reactive to least reactive.
1. A + D+ righ tarrow A+ + D
2. C+ + D righ tarrow C + D+
3. B+ + D righ tarrow B + D+
4. B + C+ righ tarrow B+ + C
A. Most reactive
B. Least reactive

Answers

Answer:

A Reaction

3. Pt(NO₃)₂(aq) + Cu(s)

4. Cr(s) + H₂SO₄(aq)

B Non Reaction

1. Mn(s) + Ca(NO₃)₂(aq)

2. KOH(aq) +  Fe(s)

Y > Q > W > Z > X

Explanation:

The first question is whether a reaction will occur base on the chemical equation below.

1. Mn(s) + Ca(NO₃)₂(aq)

2. KOH(aq) +  Fe(s)

3. Pt(NO₃)₂(aq) + Cu(s)

4. Cr(s) + H₂SO₄(aq)

Firstly, some element are more reactive than others , base on this criteria element can be arranged  base on it reactivity .

1. Mn(s) + Ca(NO₃)₂(aq)

This reaction will not occur because Mn cannot displace Ca in it compound. Usually, more reactive element displaces less reactive element.

2. KOH(aq) +  Fe(s)

The reaction will not occur since Iron is less reactive and lower in the reactivity series than potassium . So iron won't be able to displace potassium.

3. Pt(NO₃)₂(aq) + Cu(s)

Copper is more reactive than platinum so it will displace platinum easily . The reaction will definitely occur.

4. Cr(s) + H₂SO₄(aq)

Chromium is higher up in the reactivity series than hydrogen so, it will definitely displace hydrogen in it compound . The reaction will occur in this case.

Base on the reaction

Q + W+ Reaction occurs

Since the reaction occurred element Q is more reactive as it displace element w from it compound.  

X + Z+ No reaction

No reaction occurred because element x is less reactive than z therefore, it cannot displace z from it compound.

W + Z+ Reaction occurs

Element w is more reactive than z as it displaces z form it compound.

Q+ + Y Reaction occurs

Element Y is more reactive than element  Q as it displaces Q from it compound.

Therefore, the  order of reactivity from the most reactive to the least reactive will be Y > Q > W > Z > X

A. The beakers in which a chemical reaction will occur:

3. Pt(NO₃)₂(aq) + Cu(s)

4. Cr(s) + H₂SO₄(aq)

B. The beakers in which there is no reaction:

1. Mn(s) + Ca(NO₃)₂(aq)

2. KOH(aq) +  Fe(s)

C. The elements from most reactive to least reactive is:

Y > Q > W > Z > X

Solving for each part:

A.

1. Mn(s) + Ca(NO₃)₂(aq)

2. KOH(aq) +  Fe(s)

3. Pt(NO₃)₂(aq) + Cu(s)

4. Cr(s) + H₂SO₄(aq)

Elements can be arranged on the basis of reactivity:

1. Mn(s) + Ca(NO₃)₂(aq)

This reaction will not occur because Mn cannot displace Ca in it compound. Usually, more reactive element displaces less reactive element.

2. KOH(aq) +  Fe(s)

The reaction will not occur since Iron is less reactive and lower in the reactivity series than potassium . So iron won't be able to displace potassium.

3. Pt(NO₃)₂(aq) + Cu(s)

Copper is more reactive than platinum so it will displace platinum easily . The reaction will definitely occur.

4. Cr(s) + H₂SO₄(aq)

Chromium is higher up in the reactivity series than hydrogen so, it will definitely displace hydrogen in it compound . The reaction will occur in this case.

According to reactions:

Q + W→ Reaction occurs

Since the reaction occurred element Q is more reactive as it displace element w from it compound.  

X + Z →No reaction

No reaction occurred because element X is less reactive than Z therefore, it cannot displace z from it compound.

W + Z→ Reaction occurs

Element W is more reactive than Z as it displaces Z form it compound.

Q + Y →Reaction occurs

Element Y is more reactive than element Q as it displaces Q from it compound.

Thus, the order of reactivity from the most reactive to the least reactive will be: Y > Q > W > Z > X

Find more information about Reactivity series here:

brainly.com/question/17469010

A liquid solvent is added to a flask containing an insoluble solid. The total volume of the solid and liquid together is 93.0 mL. The liquid solvent has a mass of 33.7 g and a density of 0.865 g/mL. Determine the mass of the solid given its density is 3.50 g/mL

Answers

Answer:

Mass of solid = 189.141 gram

Explanation:

Given:

Total volume = 93 ml

Mass of liquid = 33.7 gram

Density of liquid = 0.865 g/ml

Density of solid = 3.50 g/ml

Find:

Mass of solid = ?

Computation:

Volume of liquid = Mass of liquid / Density of liquid

Volume of liquid = 33.7 / 0.865

Volume of liquid = 38.9595 ml

Volume of solid = Total volume - Volume of liquid

Volume of solid = 93 - 38.9595

Volume of solid = 54.0405 ml

Mass of solid = Volume of solid × Density of solid

Mass of solid = 54.0405 ml × 3.50 g/ml

Mass of solid = 189.141 gram

A gas at 350 K and 12 atm has a molar volume 12 per cent larger than that calculated from the perfect gas law. Calculate (i) the compression factor under these conditions and (ii) the molar volume of gas. Which are dominating in the sample, the attractive or repulsive forces

Answers

Answer:

(i)The compression factor is 1.12

(ii) The molar volume of the gas is 2.68 L/mol

Since the compression factor is greater than 1, the attractive forces are dominating.

Explanation: Please see the attachments below

1) How many kJ are absorbed when 45.2 g of water at 31.3 oC is heated to 76.9 oC? 2) Calculate the total heat released in kcal when 72.1 g water at 25.2 oC is cooled to 0 oC and freezes. 3) How many kilojoules are required to heat 55,500 mg of gold with specific heat = 0.129 J/g oC is heated from 24.6 oC to 123.4 oC? 4) Calculate the heat needed in kcal to change 45.6 g of water at 100 oC to change into steam.

Answers

Answer:

1. Q = 8.66 KJ

2. Q = 7.58 Kcal

3. Q = 0.71 KJ

4. Q = 24.31 Kcal

Explanation:

1. The quantity of heat absorbed can be determined by:

       Q = mcΔθ

where: Q is the quantity of heat absorbed or released, m is the mass of the substance, c is the specific heat capacity of water = 4.2 j/g[tex]^{0}C[/tex] and Δθ is the change in temperature.

           = 45.2 × 4.2  × (76.9 - 31.3)

           = 8656.704

∴       Q = 8.66 KJ

The quantity of heat absorbed is 8.66 KJ.

2. Q = mcΔθ + mL

Where L is the latent heat of fusion of ice = 334 J.

       = m(cΔθ + L)

       = 72.1(4.2 × 25.2 + 334)

   Q = 31712.464 J

       = 7579.466 calories

The total heat released is 7.58 Kcal.

3. Q = mcΔθ

      = 55.5 × 0.129 × (123.4 - 24.6)

     = 707.3586

The quantity of heat required to increase the temperature of gold is 0.71 KJ.

4. Q = mL

Where: L is the specific latent heat of vaporization = 533 calories.

     Q  = 45.6 × 533

      = 24304.8

The quantity of heat required to change water to steam is 24.31 Kcal.

Which describes the correct procedure when converting a number from scientific notation to standard notation? If the power of 10 is positive, move the decimal point to the left. If the power of 10 is positive, move the decimal point to the right. If the number being converted is greater than 10, move the decimal point to the left. If the number being converted is greater than 10, move the decimal point to the right.

Answers

Answer:

option 2

Explanation:

If the power of ten is positive, you move the decimal place to the right when converting  a number from scientific to standard notation

For example:

5.6894 * 10^9

10^9 is 1 with 9 zeros

5.6894 * 1000000000

5689400000.

it moved right

If the power of 10 is positive, move the decimal point to the left.

If the power of 10 is positive, move the decimal point to the right.

If the number being converted is greater than 10, move the decimal point to the left.

If the number being converted is greater than 10, move the decimal point to the right.

This is option 2

The correct answer is if the power of 10 is positive, move the decimal point to the right.

What is scientific notation?

A frequently-used floating-point system in which integers are expressed as products of a number between 1 and 10 multiplied by a power of 10.

Learn more about scientific notation here:-

https://brainly.com/question/2890945

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