1. In the tests with NaI/acetone and AgNO3/ethanol, as described in the experiment, it was found that benzyl chloride (PhCH2Cl) reacts in both tests. Why is this compound able to react under both conditions

Answers

Answer 1

Answer:

See explanation

Explanation:

Let us remember that the Iodide ion is a good nucleophile.  SN2 reaction is  promoted in a polar aprotic solvents like  acetone.

Aprotic solvents like acetone do not favor the formation of a carbocation hence the reaction of Sodium iodide in acetone with PhCH2Cl proceeds by SN2 mechanism. This is possible because the compound possesses a halogen atom(Cl) which is easily replaced by I^- from NaI. The corresponding NaCl formed is insoluble in acetone.

Similarly, when AgNO3/ethanol reacts with PhCH2Cl; ethanol which is a polar protic solvent and a poor nucleophile coordinates with the silver ion in the  PhCH2Cl and enhances carbocation formation (SN1 mechanism operates).

The SN2 mechanism is not followed here because there is no good nucleophile present compared to the situation in the reaction of PhCH2Cl with NaI/acetone.


Related Questions

A sample of air has a volume of 140.0 mL at 67°C.
At what temperature would its volume be 50.0 mL at
constant pressure?

Answers

Answer:

  about 121.5 K or -151.7 °C

Explanation:

Volume of an ideal gas is proportional to the absolute temperature. At 67 °C, the absolute temperature is 67+273.15 K, or 340.15 K.

Then 50.0/140.0 times that temperature is ...

  (5/14)(340.15 K) ≈ 121.482 K ≈ -151.668 °C

The volume would be 50.0 mL at a temperature of about 121.5 K or -151.7 °C.

Liquid octane reacts with gaseous oxygen gas to produce gaseous carbon dioxide and gaseous water . If of carbon dioxide is produced from the reaction of of octane and of oxygen gas, calculate the percent yield of carbon dioxide. Be sure your answer has the correct number of significant digits in it.

Answers

The question is incomplete; the complete question is;

Liquid octane CH3CH26CH3 reacts with gaseous oxygen gas O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O. If 2.80g of carbon dioxide is produced from the reaction of 3.4g of octane and 5.9g of oxygen gas, calculate the percent yield of carbon dioxide. Be sure your answer has the correct number of significant digits in it.

Answer:

55%

Explanation:

The balanced equation is:

C8H18(g) + 25/2O2(g) ----------> 8CO2(g) + 9H2O(g)

The limiting reactant IS first determined. This is the reactant that yields the least amount of product.

3.4 g octane / 114 g/mol = 0.030 mol octane

From the reaction equation;

1 mole of octane yields 8 moles of CO2

0.030 mol octane yields 0.030 * 8/1 = 0.24 moles of CO2

5.9 g O2 / 32 g/mol = 0.18 mol O2

25/2 moles of O2 yields 8 moles of CO2

0.18 moles of O2 yields 8 * 0.18/25/2 = 0.1152 moles of CO2

Oxygen is the limiting reactant.

Number of moles of carbon dioxide produced (actual yield) = 2.8 g/44g/mol = 0.0636 moles of CO2

% yield = actual yield/ theoretical yield * 100

% yield =   0.0636/0.1152 * 100= 55%

Which of the following is a chemical property?
A. Gallium metal melts in your hand.
B. Platinum does not react with oxygen at room temperature.
C. The page of the textbook is white.
D. The copper sheets that form the "skin" of the Statue of Liberty
have acquired a greenish coating over the years.

Answers

The answer is D I asked the teacher

The current, most modern view of the atom is the ___
model.

A. Rutherford
B. quantum mechanical
C. Bohr
D. Thomson
E. Einstein

Answers

Quantum mechanical! The Rutherford and Bohr models have been proven false and Thompson and Einstein never made a model of the atom.

How many moles of iron are needed to react with 0.125 moles of oxygen
Given; 4Fe + 3O2 = 2Fe2O3

Answers

Answer:

0.167 mol Fe

Explanation:

4 Fe  +  3 O₂  ⇒  2 Fe₂O₃

Convert moles of oxygen to moles of iron using the mole ratio.  You can find the mole ratio using the chemical equation.  For every 4 moles of iron, you will need 3 moles of oxygen.

(0.125 mol O₂)  (4 mol Fe/3 mol O₂) = 0.167 mol Fe

Answer:

Your mom says to stop cheating

Explanation:

g what is ΔG for the reaction at 298K, when the partial pressure of C2H4 is 0.275 atm, the partial pressure of H2O is 0.350 atm, and the partial pressure of C2H5OH is 0.100 atm?

Answers

Answer:

[tex]\Delta G=8015\frac{J}{mol}[/tex]

Explanation:

Hello.

In this case, for the following chemical reaction in gaseous phase:

[tex]C_2H_4+H_2O\rightleftharpoons C_2H_5OH[/tex]

We can write the equilibrium expression as:

[tex]Kp=\frac{p_{C_2H_5OH}}{p_{H_2O}*p_{C_2H_4}}[/tex]

it means that given the pressures, we can compute Kp as shown below:

[tex]Kp=\frac{0.100atm}{0.275atm*0.350atm}=1.04[/tex]

Next, we compute Kc at 298 K:

[tex]Kc=\frac{Kp}{(RT)^{1-1-1}}=\frac{Kp}{(RT)^{-1}}[/tex]

Whereas 1-1-1 comes from the stoichiometric coefficients of products minus reactants. Therefore, Kc is:

[tex]Kc=\frac{1.04}{(0.08206*298)^{-1}}=25.4[/tex]

Thus, the Gibbs free energy for this reaction is:

[tex]\Delta G=RTln(kC)=8.314\frac{J}{mol*K}*298K*ln(25.4)\\ \\\Delta G=8015\frac{J}{mol}[/tex]

Best regards!

which element has one electron in its fourth and outermost main energy level

Answers

Answer:K,Potassium

Explanation:

PLEASE HELP ME!!!
Which of these is measured during a scientific investigation?

Group of answer choices

Test variable (independent variable)

Outcome variable (dependent variable)

Control group

Hypothesis

Answers

Answer:

Outcome Variable

Explanation:

Control group and Hypothesis are not what your measuring.

Test variable would be like- "amount of water added"

Outcome variable would be something like- "amount plants grew"

You would be measuring the amounts the plants grew, based on the water added.

A sample of an ideal gas has a volume of 2.29 L at 285 K and 1.12 atm. Calculate the pressure when the volume is 1.33 L and the temperature is 302 K.

Answers

Answer:

[tex]P_2=2.04atm[/tex]

Explanation:

Hello.

In this case, by using the combined ideal gas law, we can identify the change in pressure, temperature an volume as shown below:

[tex]\frac{P_1V_1}{T_1} =\frac{P_2V_2}{T_2}[/tex]

In such a way, since we are asked to compute the final pressure, P2, we proceed as follows:

[tex]P_2=\frac{P_1V_1T_2}{T_1V_2} \\\\P_2=\frac{1.12atm*2.29L*302K}{285K*1.33L}\\ \\P_2=2.04atm[/tex]

Best regards!

Give the complete ionic equation for the reaction that occurs when aqueous solutions of sodium sulfide and iron(II) nitrate are mixed.

Answers

Answer:

2 Na⁺(aq) + S²⁻(aq) + Fe²⁺(aq) + 2 NO₃⁻(aq) ⇒ FeS(s) + 2 Na⁺(aq) + 2 NO₃⁻(aq)

Explanation:

Let's consider the molecular equation that occurs when aqueous solutions of sodium sulfide and iron(II) nitrate are mixed.

Na₂S(aq) + Fe(NO₃)₂ ⇒ FeS(s) + 2 NaNO₃(aq)

The complete ionic equation includes all the ions and the species that do not dissociate in water.

2 Na⁺(aq) + S²⁻(aq) + Fe²⁺(aq) + 2 NO₃⁻(aq) ⇒ FeS(s) + 2 Na⁺(aq) + 2 NO₃⁻(aq)

The complete ionic equation for the reaction between aqueous solution of sodium sulfide and iron(II) nitrate is

2Na⁺(aq) + S²⁻(aq) + Fe²⁺(aq) + 2NO₃⁻(aq) —> FeS(s) + 2Na⁺(aq) + 2NO₃⁻(aq)

The complete ionic equation for the reaction between aqueous solution of sodium sulfide and iron(II) nitrate can be written as follow:

In solution, Na₂S and Fe(NO₃)₂ will dissociate as follow:

Na₂S(aq) —> 2Na⁺(aq) + S²¯(aq)

Fe(NO₃)₂(aq) —> Fe²⁺(aq) + 2NO₃¯(aq)

The reaction will proceeds as illustrated below to give the complete ionic equation:

Na₂S(aq) + Fe(NO₃)₂(aq)—>

2Na⁺(aq) + S²¯(aq) + Fe²⁺(aq) + 2NO₃¯(aq) —> FeS(s) + 2Na⁺(aq) + 2NO₃¯(aq)

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AgCL would be least soulble at 25 degrees Celcius in ___ A. pure water B. 0.1 M HNO3 C. 0.1 M CaCl2 D. 0.1 M HCL E. It is equally soluble in all of these substances.

Answers

Answer: The answer is C. 0.1MCaCl2

Explanation:

We have AgCl whose least solubility is to be determined at 25degree Celsius

so upon looking at the options given we observe C 0.1MCaCl2 and D 0.1MHCl both have chlorine ions present and we know that here common ion effect will happen that causes decreases the solubility of the AgCl here

but when Calcium chloride dissociates it gives 2 moles of chlorine ions

[tex]CaCl2[/tex]→[tex]Ca^+2 + 2Cl^-[/tex]

so chlorine ion will be present in more amount [tex]2*0.1\\[/tex]=[tex]0.2[/tex] as compared to the chlorine produced by HCl

[tex]HCl[/tex]→[tex]H^+ +Cl^-[/tex] only 1 mole of chlorine is produced.

Hence AgCl will be least soluble in 0.1M CaCl2

Why does the liquid in a thermometer go down when it is placed in ice water?
The cold of the ice makes the liquid condense?
The surrounding air is too hot?
The density is decreasing with the temperature?
The liquid is attracted to the cold?

Answers

Answer: A) Cold ice makes the liquid condense

On the flip side, warm temperatures make the liquid expand. Since there is only one direction to go, the liquid expands upward until it reaches a certain marker on the thermometer, to indicate the temperature.

Correct answer would be A

4. Which of the following is the most stable isotope?
Polonium-210
Uranium-237
Francium-227
Plutonium-238
Half-life
(hr)
3,310
162
0.04
768,000
A. Polonium-210
B. Uranium-237
C. Francium-227
D. Plutonium-238

Answers

D. Plutonium-238 is the most stable isotope

Further explanation

Radioactivity is the process of unstable isotopes to stable isotopes by decay, by emitting certain particles (such as alpha (α), beta (β), gamma (γ) particles)

General formulas used in decay:

[tex]\large {\boxed {\bold {N_t = N_0 (\dfrac {1} {2}) ^ {t / t \frac {1} {2}}}}[/tex]

T = duration of decay

t 1/2 = half-life

N₀ = the number of initial radioactive atoms

Nt = the number of radioactive atoms left after decaying during T time

Half-life shows the time it takes for an atom to get half of its initial mass (to decay to half of its initial mass)

The longer the half-life indicates the stability of the atom

Half-life (hr) of isotopes :

Polonium-210  : 3,310

Uranium-237  : 162

Francium-227  : 0.04

Plutonium-238 : 768,000

The half-life value above shows that Plutonium-238 has the longest time, making it the most stable

The muscles of the body are part of the musculoskeletal system but would not operate without the
impulses that cause the muscles to act.
A cardiovascular
B. respiratory
C nervous
D reproductive

Answers

Answer:

C

Explanation:

The nervous system sends signals, or in this case, impulses to parts of your body that direct them to move.

the reaction A->B is second order in A and the rate constant is 0.039L/mol s. if it took 23 sec for the concentration of A to decrease to 0.30 M, what was the starting concentration of A

Answers

Answer:

0.41 M

Explanation:

A -> B

rate constant (k) = 0.039L/mol s

t = 23

Final concentration, [A]  = 0.30M

Initial concentration, [A]o = x

1 / [A]  = kt + 1 / [A]o

1 / [A]o = 1 / [A] - kt

1 / [A]o  = 1 / 0.30   - 0.039 (23)

1 / [A]  = 3.33 -  0.897 = 2.433

[A] = 0.41 M

After 0.050 mole of hydrofluoric acid is dissolved in 200 mL of aqueous solution, it is found that 7.90% of the acid is dissociated at equilibrium. Calculate the equilibrium concentrations of H3O , undissociated hydrofluoric acid (HF), and conjugate weak base of hydrofluoric acid.

Answers

Answer:

[HF] = 0.23M

0.02M = [F⁻]

[H₃O⁺] = 0.02M

Explanation:

The equilibrium of HF with water is:

HF + H₂O ⇄ H₃O⁺ + F⁻

Where F⁻ is the conjugate base of the HF

The initial concentration of HF is:

[HF] = 0.0500mol / 0.200L = 0.25M

Now, in equilibrium, if the 7.90% is dissociated, the undissociated HF is the 100 - 7.90 = 92.1%

0.25M*92.1% = 0.23M = [HF]

The conjugate base will be 0.25M - 0.23M = 0.02M = [F⁻]

And as the H₃O⁺ ion comes from the same equilibrium of F⁻ and is produced in the same proportion:

[H₃O⁺] = 0.02M

How many electrons can have the following quantum numbers in an atom: n =
3,1 = 2? Explain.

Answers

10 e


Explanation:
The idea here is that you must use the value of the angular momentum quantum number, m1 which tells you the energy subshell in which an electron resides, to find the possible values of the magnetic quantum number.

The number of values that the magnetic quantum number can take tells you the number of orbitals that are present in
So, you know that the magnetic quantum number depends on the value of the angular momentum quantum numberml={−l,−(1−1),...,−1,−0,+1,...,+(l−1),+l}
In your case, you have
l=2
, which is an accepted value for the angular momentum quantum number given the fact that the principal quantum number,
n
, is equal to
3
, so you can say thatml={−2,−1,−0,+1,+2}

This tells you that the
d
subshell, which is denoted by
l=2
, holds a total of 5 orbitals.
Since each orbital can hold a maximum of 2 electrons, one having spin-up and one having spin-down, you can say that you have 5 orbitals⋅2 e−1 orbital=10 e−

Therefore, a maximum number of
10
electrons can share these two quantum numbers in an atom.
n=3
,
l=2

These electrons are located on the third energy level, in the
3d
hope this helps

A flask contains 15.5mL of hydrogen that was collected under a pressure of
22.5 kPa. What pressure would have been required for the volume of the gas
to have been 9.00mL, assuming the same temperature?*

Answers

38.75 kPa

P1 x V1 = P2 x V2

what element is found in gruop 6 and period 4

Answers

The element that is found in group 6 and period 4 is Chromium.

Round the following number to 4 significant figures... 11278.30 *
1 point
11280
1128
11278
78.30

Answers

Answer:

11280

Explanation:

the chemical formula of tetraphosphorus hexasulfide

Answers

Answer:

Molecular Formula

P4S6

Molecular Weight

316.3 g/mol

P[tex]_4[/tex]S[tex]_6[/tex] is the chemical formula of tetraphosphorus hexasulfide. These can only include one typographic line containing symbols.

A chemical formula is a way to describe the chemical ratios of the atoms that make up a specific chemical compound or molecule in chemistry. Chemical element numbers, symbols, and on occasion other symbols, including parentheses, dashes, brackets, commas, and plus (+) and minus () signs, are used to represent the chemical elements. Which may also include subscripts or superscripts. Since a chemical formula inherently wordless, it cannot be considered a chemical name. A chemical formula does not equal a complete chemical structural formula, despite the fact that it may suggest certain basic chemical structures. P[tex]_4[/tex]S[tex]_6[/tex] is the chemical formula of tetraphosphorus hexasulfide.

To know more about chemical formula, here:

https://brainly.com/question/32018188

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Which of the following molecules would be expected to have a trigonal planar geometry?

a
NH3

b
CH4

c
H2O

d
CH2O

Answers

Answer:

CH2O

Explanation:

According to the valence shell electron pair repulsion theory, electron pairs tend to position themselves as far apart in space as possible to minimize repulsion.

The shape of a molecule depends on the number of electron pairs present on the valence shell of the central atom in the molecule- both lone pairs and bond pairs.

CH2O has three electron domains. the possession of three electron domains and no lone pairs of electrons on the central atom corresponds to a trigonal planar geometry.

What are the BCNOs in relation to the periodic table?

Answers

Answer:

Binding properties

Explanation:

How many molecules of water are produced when 8.93 * 1023 molecules of oxygen are reacted with
excess hydrogen gas in the reaction below?
2H2 + O2 → 2H2O

Answers

Answer: 1.79 x 10^24 molecules H2O

Explanation:

Use the following conversion factors to convert from molecules of oxygen to molecules of water: 1 mole O2/ 6.02 x 10^23 molecules O2, 2 mole H2O/ 1 mole O2, 6.02 x 10^23 molecules H2O/ 1 moles H2O

Find the volume in liters of 2.00 * 10 ^ 23 molecules of F2 at STP?

Answers

I think the answer is 20,000

Which conclusion can be drawn from a cathode ray being deflected toward the positive plate?
A. Atoms are indivisible.
B. There is gas in the tube.
C. A magnetic field is produced.
D. The particles of the ray are negatively charged.

Answers

Answer:

D

Explanation:

The cathode rays are being deflected towards the positive plate because the particles of the ray are negatively charged

Explanation:

The cathode ray is a beam of electrons emerging from the negatively charged electrode (cathode) in a vacuum.They have a negative electric charge.Being negatively charged they are attracted by the positive charge.They possess the properties of a particle.They travel in a straight line, perpendicular to the cathode surface.They cause ionization of gas through which they pass.

So, from this, we can conclude that the cathode rays are being deflected towards the positive plate because the particles of the ray are negatively charged.

Learn more about cathode rays here:

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will gave a brain thingy. What are the conditions required for natural selection? Check all that apply.

overproduction of offspring
same traits among all organisms in a population
variation among organisms in a population
favorable adaptations selected by nature
unfavorable adaptations passed on to offspring in larger numbers
favorable adaptations building in population over time

Answers

Answer:

everything.

Explanation:

You need nice weather,good realation ships as well as convection

Answer:

A C D F

Explanation:

Name the monosaccharides that make up each of the
disaccharides and give a common food source of each disaccharide.

Answers

Answer:

Glucose. Fructose. Galactose.

Explanation:

Glucose +fructose=succrose(normal sugar)

Glucose+Glucose= Maltose(wheat sugar)

Glucose+Galactose= Lactose(milk sugar)

What type of bonding around a central atom would result in a trigonal planar
molecule?
A. Three groups bound to it with no lone pairs
B. One group bound to it with two lone pairs
C. Three groups bound to it with one lone pair
D. Four groups bound to it with no lone pairs

Answers

Explanation:

A. 3 groups bound to it with no lone pairs

if the rate of appearance of no2 is equal to 8.00mol/min at a particular moment, what is the rate of dissapearce of N2O5 at that moment

Answers

Answer:

[tex]r_{N_2O_5}=-4.00mol/min\[/tex]

Explanation:

Hello.

In this case, since the chemical reaction is:

[tex]2N_2O_5\rightarrow 4NO_2+O_2[/tex]

We can write the rate ratio between N2O5 and NO2 as shown below:

[tex]\frac{1}{-2} r_{N_2O_5}= \frac{1}{4} r_{NO_2}[/tex]

Since N2O5 is consumed and NO2 produced at a rate of 8.00 mol/s, therefore, the rate of disappearance is N2O5 is:

[tex]r_{N_2O_5}= \frac{-2}{4} r_{NO_2}\\\\ r_{N_2O_5}=\frac{-1}{2} *8.00 mol/min\\\\ r_{N_2O_5}=-4.00mol/min[/tex]

Which is negative since N2O5 is a reactant.

Best regards!

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